Cargando…
(S)-1,2-Dimethyl-1,1,2-triphenyl-2-(4-piperidiniomethyl)disilane chloride
The title compound, C(26)H(34)NSi(2) (+)·Cl(−), shows chirality at silicon. Because of its highly selective synthesis with an e.r. of >99:1 by means of a racemic resolution with mandelic acid, the free disilane is of great importance to the chemistry of highly enantiomerically enriched lithiosi...
| Autores principales: | , , |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959254/ https://www.ncbi.nlm.nih.gov/pubmed/21201154 http://dx.doi.org/10.1107/S1600536808028808 |