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[1,3-Bis(diphenylphosphino)propane-κ(2) P,P′]diiodido(perfluoropropyl)rhodium(III) dichloromethane solvate
The structure of the title compound, [RhI(2)(C(3)F(7))(C(27)H(26)P(2))]·CH(2)Cl(2), at 110 (2) K is an unusual example of a structurally characterized square-based pyramidal alkyl complex of rhodium(III). The Rh—C bond is relatively short at 1.996 (6) Å. This short metal–carbon bond length is typica...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959266/ https://www.ncbi.nlm.nih.gov/pubmed/21201064 http://dx.doi.org/10.1107/S1600536808029978 |