[1,3-Bis(diphenyl­phosphino)propane-κ(2) P,P′]diiodido(perfluoro­propyl)rhodium(III) dichloro­methane solvate

The structure of the title compound, [RhI(2)(C(3)F(7))(C(27)H(26)P(2))]·CH(2)Cl(2), at 110 (2) K is an unusual example of a structurally characterized square-based pyramidal alkyl complex of rhodium(III). The Rh—C bond is relatively short at 1.996 (6) Å. This short metal–carbon bond length is typica...

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Detalles Bibliográficos
Autores principales: Panthi, Basu, Gipson, Stephen L., Franken, Andreas
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959266/
https://www.ncbi.nlm.nih.gov/pubmed/21201064
http://dx.doi.org/10.1107/S1600536808029978
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author Panthi, Basu
Gipson, Stephen L.
Franken, Andreas
author_facet Panthi, Basu
Gipson, Stephen L.
Franken, Andreas
author_sort Panthi, Basu
collection PubMed
description The structure of the title compound, [RhI(2)(C(3)F(7))(C(27)H(26)P(2))]·CH(2)Cl(2), at 110 (2) K is an unusual example of a structurally characterized square-based pyramidal alkyl complex of rhodium(III). The Rh—C bond is relatively short at 1.996 (6) Å. This short metal–carbon bond length is typical of perfluoro complexes of transition metals and illustrates the enhanced bond strength in these compounds.
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spelling pubmed-29592662010-12-30 [1,3-Bis(diphenyl­phosphino)propane-κ(2) P,P′]diiodido(perfluoro­propyl)rhodium(III) dichloro­methane solvate Panthi, Basu Gipson, Stephen L. Franken, Andreas Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, [RhI(2)(C(3)F(7))(C(27)H(26)P(2))]·CH(2)Cl(2), at 110 (2) K is an unusual example of a structurally characterized square-based pyramidal alkyl complex of rhodium(III). The Rh—C bond is relatively short at 1.996 (6) Å. This short metal–carbon bond length is typical of perfluoro complexes of transition metals and illustrates the enhanced bond strength in these compounds. International Union of Crystallography 2008-09-27 /pmc/articles/PMC2959266/ /pubmed/21201064 http://dx.doi.org/10.1107/S1600536808029978 Text en © Panthi et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Panthi, Basu
Gipson, Stephen L.
Franken, Andreas
[1,3-Bis(diphenyl­phosphino)propane-κ(2) P,P′]diiodido(perfluoro­propyl)rhodium(III) dichloro­methane solvate
title [1,3-Bis(diphenyl­phosphino)propane-κ(2) P,P′]diiodido(perfluoro­propyl)rhodium(III) dichloro­methane solvate
title_full [1,3-Bis(diphenyl­phosphino)propane-κ(2) P,P′]diiodido(perfluoro­propyl)rhodium(III) dichloro­methane solvate
title_fullStr [1,3-Bis(diphenyl­phosphino)propane-κ(2) P,P′]diiodido(perfluoro­propyl)rhodium(III) dichloro­methane solvate
title_full_unstemmed [1,3-Bis(diphenyl­phosphino)propane-κ(2) P,P′]diiodido(perfluoro­propyl)rhodium(III) dichloro­methane solvate
title_short [1,3-Bis(diphenyl­phosphino)propane-κ(2) P,P′]diiodido(perfluoro­propyl)rhodium(III) dichloro­methane solvate
title_sort [1,3-bis(diphenyl­phosphino)propane-κ(2) p,p′]diiodido(perfluoro­propyl)rhodium(iii) dichloro­methane solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959266/
https://www.ncbi.nlm.nih.gov/pubmed/21201064
http://dx.doi.org/10.1107/S1600536808029978
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AT gipsonstephenl 13bisdiphenylphosphinopropanek2ppdiiodidoperfluoropropylrhodiumiiidichloromethanesolvate
AT frankenandreas 13bisdiphenylphosphinopropanek2ppdiiodidoperfluoropropylrhodiumiiidichloromethanesolvate

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