Penta­carbonyl-1κ(2) C,2κ(3) C-(ferrocenyl­diphenyl­phosphine-1κP)[μ-2-(4-methyl­phen­yl)-2-aza­propane-1,3-dithiol­ato-1:2κ(4) S,S′:S,S′]diiron(I)(Fe—Fe)

The title compound, [Fe(2)(C(9)H(11)NS(2)){Fe(C(5)H(5))(C(17)H(14)P)}(CO)(5)], was prepared as an aza­dithiol­ato–iron model for the iron-only hydrogenase active site. The Fe(2)S(2) unit exhibits a butterfly conformation and the ferrocenyldiphenyl­phosphine ligand is trans to the Fe—Fe bond. The Fe—...

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Detalles Bibliográficos
Autores principales: Tang, Yan-Feng, Zhu, Jin-Li
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959581/
https://www.ncbi.nlm.nih.gov/pubmed/21580868
http://dx.doi.org/10.1107/S1600536808032698

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959581/
https://www.ncbi.nlm.nih.gov/pubmed/21580868
http://dx.doi.org/10.1107/S1600536808032698

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