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Pentacarbonyl-1κ(2) C,2κ(3) C-(ferrocenyldiphenylphosphine-1κP)[μ-2-(4-methylphenyl)-2-azapropane-1,3-dithiolato-1:2κ(4) S,S′:S,S′]diiron(I)(Fe—Fe)
The title compound, [Fe(2)(C(9)H(11)NS(2)){Fe(C(5)H(5))(C(17)H(14)P)}(CO)(5)], was prepared as an azadithiolato–iron model for the iron-only hydrogenase active site. The Fe(2)S(2) unit exhibits a butterfly conformation and the ferrocenyldiphenylphosphine ligand is trans to the Fe—Fe bond. The Fe—...
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959581/ https://www.ncbi.nlm.nih.gov/pubmed/21580868 http://dx.doi.org/10.1107/S1600536808032698 |
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| author | Tang, Yan-Feng Zhu, Jin-Li |
| author_facet | Tang, Yan-Feng Zhu, Jin-Li |
| author_sort | Tang, Yan-Feng |
| collection | PubMed |
| description | The title compound, [Fe(2)(C(9)H(11)NS(2)){Fe(C(5)H(5))(C(17)H(14)P)}(CO)(5)], was prepared as an azadithiolato–iron model for the iron-only hydrogenase active site. The Fe(2)S(2) unit exhibits a butterfly conformation and the ferrocenyldiphenylphosphine ligand is trans to the Fe—Fe bond. The Fe—Fe distance of 2.5160 (8) Å is longer than found in related model structures. Intramolecular C—H⋯S and intermolecular C—H⋯O hydrogen bonds are observed. |
| format | Text |
| id | pubmed-2959581 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29595812010-12-30 Pentacarbonyl-1κ(2) C,2κ(3) C-(ferrocenyldiphenylphosphine-1κP)[μ-2-(4-methylphenyl)-2-azapropane-1,3-dithiolato-1:2κ(4) S,S′:S,S′]diiron(I)(Fe—Fe) Tang, Yan-Feng Zhu, Jin-Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Fe(2)(C(9)H(11)NS(2)){Fe(C(5)H(5))(C(17)H(14)P)}(CO)(5)], was prepared as an azadithiolato–iron model for the iron-only hydrogenase active site. The Fe(2)S(2) unit exhibits a butterfly conformation and the ferrocenyldiphenylphosphine ligand is trans to the Fe—Fe bond. The Fe—Fe distance of 2.5160 (8) Å is longer than found in related model structures. Intramolecular C—H⋯S and intermolecular C—H⋯O hydrogen bonds are observed. International Union of Crystallography 2008-10-18 /pmc/articles/PMC2959581/ /pubmed/21580868 http://dx.doi.org/10.1107/S1600536808032698 Text en © Tang and Zhu 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Tang, Yan-Feng Zhu, Jin-Li Pentacarbonyl-1κ(2) C,2κ(3) C-(ferrocenyldiphenylphosphine-1κP)[μ-2-(4-methylphenyl)-2-azapropane-1,3-dithiolato-1:2κ(4) S,S′:S,S′]diiron(I)(Fe—Fe) |
| title | Pentacarbonyl-1κ(2)
C,2κ(3)
C-(ferrocenyldiphenylphosphine-1κP)[μ-2-(4-methylphenyl)-2-azapropane-1,3-dithiolato-1:2κ(4)
S,S′:S,S′]diiron(I)(Fe—Fe) |
| title_full | Pentacarbonyl-1κ(2)
C,2κ(3)
C-(ferrocenyldiphenylphosphine-1κP)[μ-2-(4-methylphenyl)-2-azapropane-1,3-dithiolato-1:2κ(4)
S,S′:S,S′]diiron(I)(Fe—Fe) |
| title_fullStr | Pentacarbonyl-1κ(2)
C,2κ(3)
C-(ferrocenyldiphenylphosphine-1κP)[μ-2-(4-methylphenyl)-2-azapropane-1,3-dithiolato-1:2κ(4)
S,S′:S,S′]diiron(I)(Fe—Fe) |
| title_full_unstemmed | Pentacarbonyl-1κ(2)
C,2κ(3)
C-(ferrocenyldiphenylphosphine-1κP)[μ-2-(4-methylphenyl)-2-azapropane-1,3-dithiolato-1:2κ(4)
S,S′:S,S′]diiron(I)(Fe—Fe) |
| title_short | Pentacarbonyl-1κ(2)
C,2κ(3)
C-(ferrocenyldiphenylphosphine-1κP)[μ-2-(4-methylphenyl)-2-azapropane-1,3-dithiolato-1:2κ(4)
S,S′:S,S′]diiron(I)(Fe—Fe) |
| title_sort | pentacarbonyl-1κ(2)
c,2κ(3)
c-(ferrocenyldiphenylphosphine-1κp)[μ-2-(4-methylphenyl)-2-azapropane-1,3-dithiolato-1:2κ(4)
s,s′:s,s′]diiron(i)(fe—fe) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959581/ https://www.ncbi.nlm.nih.gov/pubmed/21580868 http://dx.doi.org/10.1107/S1600536808032698 |
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