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Pentacarbonyl-1κ(2) C,2κ(3) C-(ferrocenyldiphenylphosphine-1κP)[μ-2-(4-methylphenyl)-2-azapropane-1,3-dithiolato-1:2κ(4) S,S′:S,S′]diiron(I)(Fe—Fe)

The title compound, [Fe(2)(C(9)H(11)NS(2)){Fe(C(5)H(5))(C(17)H(14)P)}(CO)(5)], was prepared as an azadithiolato–iron model for the iron-only hydrogenase active site. The Fe(2)S(2) unit exhibits a butterfly conformation and the ferrocenyldiphenylphosphine ligand is trans to the Fe—Fe bond. The Fe—...

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Detalles Bibliográficos
Autores principales:	Tang, Yan-Feng, Zhu, Jin-Li
Formato:	Texto
Lenguaje:	English
Publicado:	International Union of Crystallography 2008
Materias:	Metal-Organic Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959581/ https://www.ncbi.nlm.nih.gov/pubmed/21580868 http://dx.doi.org/10.1107/S1600536808032698

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