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rac-Carbonyl{1-[(diphenylphosphino)methyl]ethanethiolato}(triphenylphosphine)rhodium(I)
The title compound, [Rh(C(15)H(16)PS)(C(18)H(15)P)(CO)], was synthesized from the reaction of the ligand rac-[Ph(2)PCH(2)CH(CH(3))SH] with trans-[Rh(F)(CO)(PPh(3))(2)] in a 1:1 molar ratio in toluene. The Rh atom is four-coordinated in a distorted square-planar geometry with the P—S ligand [Ph(2)PCH...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959607/ https://www.ncbi.nlm.nih.gov/pubmed/21580902 http://dx.doi.org/10.1107/S1600536808034284 |