rac-Carbon­yl{1-[(diphenyl­phosphino)meth­yl]ethanethiol­ato}(triphenyl­phosphine)rhodium(I)

The title compound, [Rh(C(15)H(16)PS)(C(18)H(15)P)(CO)], was synthesized from the reaction of the ligand rac-[Ph(2)PCH(2)CH(CH(3))SH] with trans-[Rh(F)(CO)(PPh(3))(2)] in a 1:1 molar ratio in toluene. The Rh atom is four-coordinated in a distorted square-planar geometry with the P—S ligand [Ph(2)PCH...

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Detalles Bibliográficos
Autores principales: Hernández-Ortega, Simón, Morales-Morales, David
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959607/
https://www.ncbi.nlm.nih.gov/pubmed/21580902
http://dx.doi.org/10.1107/S1600536808034284
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author Hernández-Ortega, Simón
Morales-Morales, David
author_facet Hernández-Ortega, Simón
Morales-Morales, David
author_sort Hernández-Ortega, Simón
collection PubMed
description The title compound, [Rh(C(15)H(16)PS)(C(18)H(15)P)(CO)], was synthesized from the reaction of the ligand rac-[Ph(2)PCH(2)CH(CH(3))SH] with trans-[Rh(F)(CO)(PPh(3))(2)] in a 1:1 molar ratio in toluene. The Rh atom is four-coordinated in a distorted square-planar geometry with the P—S ligand [Ph(2)PCH(2)CH(CH(3))S] acting as a chelate and the PPh(3) and disordered CO [site occupation factors of 0.61 (5) and 0.39 (5)] ligands completing the coordination.
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spelling pubmed-29596072010-12-30 rac-Carbon­yl{1-[(diphenyl­phosphino)meth­yl]ethanethiol­ato}(triphenyl­phosphine)rhodium(I) Hernández-Ortega, Simón Morales-Morales, David Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Rh(C(15)H(16)PS)(C(18)H(15)P)(CO)], was synthesized from the reaction of the ligand rac-[Ph(2)PCH(2)CH(CH(3))SH] with trans-[Rh(F)(CO)(PPh(3))(2)] in a 1:1 molar ratio in toluene. The Rh atom is four-coordinated in a distorted square-planar geometry with the P—S ligand [Ph(2)PCH(2)CH(CH(3))S] acting as a chelate and the PPh(3) and disordered CO [site occupation factors of 0.61 (5) and 0.39 (5)] ligands completing the coordination. International Union of Crystallography 2008-10-25 /pmc/articles/PMC2959607/ /pubmed/21580902 http://dx.doi.org/10.1107/S1600536808034284 Text en © Hernández-Ortega and Morales-Morales 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hernández-Ortega, Simón
Morales-Morales, David
rac-Carbon­yl{1-[(diphenyl­phosphino)meth­yl]ethanethiol­ato}(triphenyl­phosphine)rhodium(I)
title rac-Carbon­yl{1-[(diphenyl­phosphino)meth­yl]ethanethiol­ato}(triphenyl­phosphine)rhodium(I)
title_full rac-Carbon­yl{1-[(diphenyl­phosphino)meth­yl]ethanethiol­ato}(triphenyl­phosphine)rhodium(I)
title_fullStr rac-Carbon­yl{1-[(diphenyl­phosphino)meth­yl]ethanethiol­ato}(triphenyl­phosphine)rhodium(I)
title_full_unstemmed rac-Carbon­yl{1-[(diphenyl­phosphino)meth­yl]ethanethiol­ato}(triphenyl­phosphine)rhodium(I)
title_short rac-Carbon­yl{1-[(diphenyl­phosphino)meth­yl]ethanethiol­ato}(triphenyl­phosphine)rhodium(I)
title_sort rac-carbon­yl{1-[(diphenyl­phosphino)meth­yl]ethanethiol­ato}(triphenyl­phosphine)rhodium(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959607/
https://www.ncbi.nlm.nih.gov/pubmed/21580902
http://dx.doi.org/10.1107/S1600536808034284
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