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[μ-10,21-Dimethyl-3,6,14,17-tetra­za­tricyclo­[17.3.1.1(8,12)]tetra­cosa-1(23),2,6,8,10,12 (24),13,17,19,21-deca­ene-23,24-diolato-κ(4) N (3),N (6),O (23),O (24):κ(4) N (14),N (17),O (23),O (24)]bis­(perchlorato-κO)dimanganese(II)

In the centrosymmetric and dinuclear title complex, [Mn(2)(C(22)H(22)N(4)O(2))(ClO(4))(2)], the two Mn atoms are bridged by two phenolate O atoms of the N(4)O(2) macrocycle with an Mn⋯Mn distance of 2.9228 (11) Å. The distorted square–pyramidal N(2)O(3) coordination geometry is completed by an O ato...

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Detalles Bibliográficos
Autores principales: Liu, Jing, Pan, Zhi-Quan, Zhou, Hong, Li, Yi-Zhi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959967/
https://www.ncbi.nlm.nih.gov/pubmed/21581126
http://dx.doi.org/10.1107/S1600536808035551