[μ-10,21-Dimethyl-3,6,14,17-tetra­za­tricyclo­[17.3.1.1(8,12)]tetra­cosa-1(23),2,6,8,10,12 (24),13,17,19,21-deca­ene-23,24-diolato-κ(4) N (3),N (6),O (23),O (24):κ(4) N (14),N (17),O (23),O (24)]bis­(perchlorato-κO)dimanganese(II)

In the centrosymmetric and dinuclear title complex, [Mn(2)(C(22)H(22)N(4)O(2))(ClO(4))(2)], the two Mn atoms are bridged by two phenolate O atoms of the N(4)O(2) macrocycle with an Mn⋯Mn distance of 2.9228 (11) Å. The distorted square–pyramidal N(2)O(3) coordination geometry is completed by an O ato...

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Detalles Bibliográficos
Autores principales: Liu, Jing, Pan, Zhi-Quan, Zhou, Hong, Li, Yi-Zhi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959967/
https://www.ncbi.nlm.nih.gov/pubmed/21581126
http://dx.doi.org/10.1107/S1600536808035551
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author Liu, Jing
Pan, Zhi-Quan
Zhou, Hong
Li, Yi-Zhi
author_facet Liu, Jing
Pan, Zhi-Quan
Zhou, Hong
Li, Yi-Zhi
author_sort Liu, Jing
collection PubMed
description In the centrosymmetric and dinuclear title complex, [Mn(2)(C(22)H(22)N(4)O(2))(ClO(4))(2)], the two Mn atoms are bridged by two phenolate O atoms of the N(4)O(2) macrocycle with an Mn⋯Mn distance of 2.9228 (11) Å. The distorted square–pyramidal N(2)O(3) coordination geometry is completed by an O atom derived from a perchlorate anion.
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spelling pubmed-29599672010-12-30 [μ-10,21-Dimethyl-3,6,14,17-tetra­za­tricyclo­[17.3.1.1(8,12)]tetra­cosa-1(23),2,6,8,10,12 (24),13,17,19,21-deca­ene-23,24-diolato-κ(4) N (3),N (6),O (23),O (24):κ(4) N (14),N (17),O (23),O (24)]bis­(perchlorato-κO)dimanganese(II) Liu, Jing Pan, Zhi-Quan Zhou, Hong Li, Yi-Zhi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric and dinuclear title complex, [Mn(2)(C(22)H(22)N(4)O(2))(ClO(4))(2)], the two Mn atoms are bridged by two phenolate O atoms of the N(4)O(2) macrocycle with an Mn⋯Mn distance of 2.9228 (11) Å. The distorted square–pyramidal N(2)O(3) coordination geometry is completed by an O atom derived from a perchlorate anion. International Union of Crystallography 2008-11-08 /pmc/articles/PMC2959967/ /pubmed/21581126 http://dx.doi.org/10.1107/S1600536808035551 Text en © Liu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Jing
Pan, Zhi-Quan
Zhou, Hong
Li, Yi-Zhi
[μ-10,21-Dimethyl-3,6,14,17-tetra­za­tricyclo­[17.3.1.1(8,12)]tetra­cosa-1(23),2,6,8,10,12 (24),13,17,19,21-deca­ene-23,24-diolato-κ(4) N (3),N (6),O (23),O (24):κ(4) N (14),N (17),O (23),O (24)]bis­(perchlorato-κO)dimanganese(II)
title [μ-10,21-Dimethyl-3,6,14,17-tetra­za­tricyclo­[17.3.1.1(8,12)]tetra­cosa-1(23),2,6,8,10,12 (24),13,17,19,21-deca­ene-23,24-diolato-κ(4) N (3),N (6),O (23),O (24):κ(4) N (14),N (17),O (23),O (24)]bis­(perchlorato-κO)dimanganese(II)
title_full [μ-10,21-Dimethyl-3,6,14,17-tetra­za­tricyclo­[17.3.1.1(8,12)]tetra­cosa-1(23),2,6,8,10,12 (24),13,17,19,21-deca­ene-23,24-diolato-κ(4) N (3),N (6),O (23),O (24):κ(4) N (14),N (17),O (23),O (24)]bis­(perchlorato-κO)dimanganese(II)
title_fullStr [μ-10,21-Dimethyl-3,6,14,17-tetra­za­tricyclo­[17.3.1.1(8,12)]tetra­cosa-1(23),2,6,8,10,12 (24),13,17,19,21-deca­ene-23,24-diolato-κ(4) N (3),N (6),O (23),O (24):κ(4) N (14),N (17),O (23),O (24)]bis­(perchlorato-κO)dimanganese(II)
title_full_unstemmed [μ-10,21-Dimethyl-3,6,14,17-tetra­za­tricyclo­[17.3.1.1(8,12)]tetra­cosa-1(23),2,6,8,10,12 (24),13,17,19,21-deca­ene-23,24-diolato-κ(4) N (3),N (6),O (23),O (24):κ(4) N (14),N (17),O (23),O (24)]bis­(perchlorato-κO)dimanganese(II)
title_short [μ-10,21-Dimethyl-3,6,14,17-tetra­za­tricyclo­[17.3.1.1(8,12)]tetra­cosa-1(23),2,6,8,10,12 (24),13,17,19,21-deca­ene-23,24-diolato-κ(4) N (3),N (6),O (23),O (24):κ(4) N (14),N (17),O (23),O (24)]bis­(perchlorato-κO)dimanganese(II)
title_sort [μ-10,21-dimethyl-3,6,14,17-tetra­za­tricyclo­[17.3.1.1(8,12)]tetra­cosa-1(23),2,6,8,10,12 (24),13,17,19,21-deca­ene-23,24-diolato-κ(4) n (3),n (6),o (23),o (24):κ(4) n (14),n (17),o (23),o (24)]bis­(perchlorato-κo)dimanganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959967/
https://www.ncbi.nlm.nih.gov/pubmed/21581126
http://dx.doi.org/10.1107/S1600536808035551
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