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Poly[4,4′-iminodipyridinium [tetra-μ(3)-oxido-tetraoxido-di-μ(4)-phosphato-κ(4) O:O′:O′′:O′′′-tetravanadium(V)]]
In the title salt, {(C(10)H(11)N(3))[V(4)O(8)(PO(4))(2)]}(n), cubane-like [V(4)O(8)](4+) clusters are connected by phosphate anions into anionic [V(4)P(2)O(16)](n) (2n−) layers. These aggregate into the three-dimensional structure via N—H⋯O hydrogen-bonding mechanisms imparted by 4,4′-iminodipyridi...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959979/ https://www.ncbi.nlm.nih.gov/pubmed/21581199 http://dx.doi.org/10.1107/S1600536808038348 |