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Pentacarbonyl-2κ(5) C-chlorido-1κCl-bis[1(η(5))-cyclopentadienyl](μ-α-oxidobenzylidene-1:2κ(2) O:C)titanium(IV)tungsten(0)
The title compound, [TiW(C(5)H(5))(2)(C(7)H(5)O)Cl(CO)(5)], consists of two metal centres, with a (tungstenpentacarbonyl)oxyphenylcarbene unit coordinated by a titanocene chloride. The oxycarbene group is nearly planar, with the phenyl ring twisted by an angle of 39.1 (2)° with respect to this p...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960115/ https://www.ncbi.nlm.nih.gov/pubmed/21581149 http://dx.doi.org/10.1107/S1600536808036465 |