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catena-Poly[[[trans-diaqua­bis(pyridine-κN)cobalt(II)]-μ-(4-{N′-[1-(3-acetyl-4-methyl-1H-pyrazol-5-yl)ethyl­idene]hydrazino}benzoato-κ(3) O:N,N′)-[bis­(pyridine-κN)cobalt(III)]-μ-(4-{N′-[1-(3-acetyl-4-methyl-1H-pyrazol-5-yl)ethyl­idene]hydrazino}benzoato-κ(3) N,N′:O)]perchlorate 3.66-hydrate]

The title compound, {[Co(2)(C(15)H(14)N(4)O(3))(2)(C(5)H(5)N)(4)(H(2)O)(2)]ClO(4)·3.66H(2)O}(n), is a one-dimensional coordination polymer, with both Co(II) and Co(III) centres in its structure. The ligand environment surrounding Co(III) is formed by two N,N-chelating pyrazole-containing ligands and...

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Detalles Bibliográficos
Autores principales: Penkova, Larysa, Azarkh, Mikhail P., Haukka, Matti, Meyer, Franc, Fritsky, Igor O.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960270/
https://www.ncbi.nlm.nih.gov/pubmed/21201374
http://dx.doi.org/10.1107/S1600536808002675