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catena-Poly[[[trans-diaquabis(pyridine-κN)cobalt(II)]-μ-(4-{N′-[1-(3-acetyl-4-methyl-1H-pyrazol-5-yl)ethylidene]hydrazino}benzoato-κ(3) O:N,N′)-[bis(pyridine-κN)cobalt(III)]-μ-(4-{N′-[1-(3-acetyl-4-methyl-1H-pyrazol-5-yl)ethylidene]hydrazino}benzoato-κ(3) N,N′:O)]perchlorate 3.66-hydrate]
The title compound, {[Co(2)(C(15)H(14)N(4)O(3))(2)(C(5)H(5)N)(4)(H(2)O)(2)]ClO(4)·3.66H(2)O}(n), is a one-dimensional coordination polymer, with both Co(II) and Co(III) centres in its structure. The ligand environment surrounding Co(III) is formed by two N,N-chelating pyrazole-containing ligands and...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960270/ https://www.ncbi.nlm.nih.gov/pubmed/21201374 http://dx.doi.org/10.1107/S1600536808002675 |
| _version_ | 1782188699126071296 |
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| author | Penkova, Larysa Azarkh, Mikhail P. Haukka, Matti Meyer, Franc Fritsky, Igor O. |
| author_facet | Penkova, Larysa Azarkh, Mikhail P. Haukka, Matti Meyer, Franc Fritsky, Igor O. |
| author_sort | Penkova, Larysa |
| collection | PubMed |
| description | The title compound, {[Co(2)(C(15)H(14)N(4)O(3))(2)(C(5)H(5)N)(4)(H(2)O)(2)]ClO(4)·3.66H(2)O}(n), is a one-dimensional coordination polymer, with both Co(II) and Co(III) centres in its structure. The ligand environment surrounding Co(III) is formed by two N,N-chelating pyrazole-containing ligands and two pyridine molecules in axial positions. The high-spin Co(II) ions, situated at crystallographic centres of inversion, exhibit a distorted octahedral coordination mode. The ClO(4) (−) anion is linked to the polymer chain via hydrogen bonds. The chains are connected by hydrogen bonds to produce a three-dimensional structure. |
| format | Text |
| id | pubmed-2960270 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29602702010-12-30 catena-Poly[[[trans-diaquabis(pyridine-κN)cobalt(II)]-μ-(4-{N′-[1-(3-acetyl-4-methyl-1H-pyrazol-5-yl)ethylidene]hydrazino}benzoato-κ(3) O:N,N′)-[bis(pyridine-κN)cobalt(III)]-μ-(4-{N′-[1-(3-acetyl-4-methyl-1H-pyrazol-5-yl)ethylidene]hydrazino}benzoato-κ(3) N,N′:O)]perchlorate 3.66-hydrate] Penkova, Larysa Azarkh, Mikhail P. Haukka, Matti Meyer, Franc Fritsky, Igor O. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {[Co(2)(C(15)H(14)N(4)O(3))(2)(C(5)H(5)N)(4)(H(2)O)(2)]ClO(4)·3.66H(2)O}(n), is a one-dimensional coordination polymer, with both Co(II) and Co(III) centres in its structure. The ligand environment surrounding Co(III) is formed by two N,N-chelating pyrazole-containing ligands and two pyridine molecules in axial positions. The high-spin Co(II) ions, situated at crystallographic centres of inversion, exhibit a distorted octahedral coordination mode. The ClO(4) (−) anion is linked to the polymer chain via hydrogen bonds. The chains are connected by hydrogen bonds to produce a three-dimensional structure. International Union of Crystallography 2008-01-30 /pmc/articles/PMC2960270/ /pubmed/21201374 http://dx.doi.org/10.1107/S1600536808002675 Text en © Penkova et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Penkova, Larysa Azarkh, Mikhail P. Haukka, Matti Meyer, Franc Fritsky, Igor O. catena-Poly[[[trans-diaquabis(pyridine-κN)cobalt(II)]-μ-(4-{N′-[1-(3-acetyl-4-methyl-1H-pyrazol-5-yl)ethylidene]hydrazino}benzoato-κ(3) O:N,N′)-[bis(pyridine-κN)cobalt(III)]-μ-(4-{N′-[1-(3-acetyl-4-methyl-1H-pyrazol-5-yl)ethylidene]hydrazino}benzoato-κ(3) N,N′:O)]perchlorate 3.66-hydrate] |
| title |
catena-Poly[[[trans-diaquabis(pyridine-κN)cobalt(II)]-μ-(4-{N′-[1-(3-acetyl-4-methyl-1H-pyrazol-5-yl)ethylidene]hydrazino}benzoato-κ(3)
O:N,N′)-[bis(pyridine-κN)cobalt(III)]-μ-(4-{N′-[1-(3-acetyl-4-methyl-1H-pyrazol-5-yl)ethylidene]hydrazino}benzoato-κ(3)
N,N′:O)]perchlorate 3.66-hydrate] |
| title_full |
catena-Poly[[[trans-diaquabis(pyridine-κN)cobalt(II)]-μ-(4-{N′-[1-(3-acetyl-4-methyl-1H-pyrazol-5-yl)ethylidene]hydrazino}benzoato-κ(3)
O:N,N′)-[bis(pyridine-κN)cobalt(III)]-μ-(4-{N′-[1-(3-acetyl-4-methyl-1H-pyrazol-5-yl)ethylidene]hydrazino}benzoato-κ(3)
N,N′:O)]perchlorate 3.66-hydrate] |
| title_fullStr |
catena-Poly[[[trans-diaquabis(pyridine-κN)cobalt(II)]-μ-(4-{N′-[1-(3-acetyl-4-methyl-1H-pyrazol-5-yl)ethylidene]hydrazino}benzoato-κ(3)
O:N,N′)-[bis(pyridine-κN)cobalt(III)]-μ-(4-{N′-[1-(3-acetyl-4-methyl-1H-pyrazol-5-yl)ethylidene]hydrazino}benzoato-κ(3)
N,N′:O)]perchlorate 3.66-hydrate] |
| title_full_unstemmed |
catena-Poly[[[trans-diaquabis(pyridine-κN)cobalt(II)]-μ-(4-{N′-[1-(3-acetyl-4-methyl-1H-pyrazol-5-yl)ethylidene]hydrazino}benzoato-κ(3)
O:N,N′)-[bis(pyridine-κN)cobalt(III)]-μ-(4-{N′-[1-(3-acetyl-4-methyl-1H-pyrazol-5-yl)ethylidene]hydrazino}benzoato-κ(3)
N,N′:O)]perchlorate 3.66-hydrate] |
| title_short |
catena-Poly[[[trans-diaquabis(pyridine-κN)cobalt(II)]-μ-(4-{N′-[1-(3-acetyl-4-methyl-1H-pyrazol-5-yl)ethylidene]hydrazino}benzoato-κ(3)
O:N,N′)-[bis(pyridine-κN)cobalt(III)]-μ-(4-{N′-[1-(3-acetyl-4-methyl-1H-pyrazol-5-yl)ethylidene]hydrazino}benzoato-κ(3)
N,N′:O)]perchlorate 3.66-hydrate] |
| title_sort | catena-poly[[[trans-diaquabis(pyridine-κn)cobalt(ii)]-μ-(4-{n′-[1-(3-acetyl-4-methyl-1h-pyrazol-5-yl)ethylidene]hydrazino}benzoato-κ(3)
o:n,n′)-[bis(pyridine-κn)cobalt(iii)]-μ-(4-{n′-[1-(3-acetyl-4-methyl-1h-pyrazol-5-yl)ethylidene]hydrazino}benzoato-κ(3)
n,n′:o)]perchlorate 3.66-hydrate] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960270/ https://www.ncbi.nlm.nih.gov/pubmed/21201374 http://dx.doi.org/10.1107/S1600536808002675 |
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