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(η(5)-Cyclopentadienyl){[3-(2,2-dicyanoethenyl)bicyclo[2.2.1]hepta-2,5-dien-2-yl]ethynyl}(triphenylphosphine)nickel(II)
The title compound, [Ni(C(5)H(5))(C(13)H(7)N(2))(C(18)H(15)P)] or (η(5)-C(5)H(5))(PPh(3))Ni—C C—C(7)H(6)—C(H)=C(CN)(2), contains an unusual disubstituted norbornadienyl (NBD) ligand containing ethynyl (–C C–) and dicyanovinyl [–C(H)=C(CN)(2)] groups. Disorder is present in the NBD group with site o...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960392/ https://www.ncbi.nlm.nih.gov/pubmed/21201357 http://dx.doi.org/10.1107/S1600536808002328 |