Penta­carbonyl-2κ(5) C-chlorido-1κCl-bis­[1(η(5))-cyclo­penta­dien­yl][μ-oxido(phenyl)methylene-1:2κ(2) O:C]hafnium(IV)tungsten(0)

The title compound, [HfW(C(5)H(5))(2)(C(7)H(5)O)Cl(CO)(5)] or [W(CO)(5)(C(7)H(5)O){Hf(C(5)H(5))(2)Cl}], contains two metal centres, with a (tungstenpenta­carbon­yl)oxy­phenyl­carbene unit coordinated to a hafnocene chloride. The Hf—O—C angle is nearly linear, and the C=O distance is slightly shorter...

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Detalles Bibliográficos
Autores principales: Esterhuysen, Catharine, Nel, I. B. Jacques, Cronje, Stephanie
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960508/
https://www.ncbi.nlm.nih.gov/pubmed/21201603
http://dx.doi.org/10.1107/S1600536808025245

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960508/
https://www.ncbi.nlm.nih.gov/pubmed/21201603
http://dx.doi.org/10.1107/S1600536808025245

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