Penta­carbonyl-2κ(5) C-chlorido-1κCl-bis­[1(η(5))-cyclo­penta­dien­yl][μ-oxido(phenyl)methylene-1:2κ(2) O:C]hafnium(IV)tungsten(0)

The title compound, [HfW(C(5)H(5))(2)(C(7)H(5)O)Cl(CO)(5)] or [W(CO)(5)(C(7)H(5)O){Hf(C(5)H(5))(2)Cl}], contains two metal centres, with a (tungstenpenta­carbon­yl)oxy­phenyl­carbene unit coordinated to a hafnocene chloride. The Hf—O—C angle is nearly linear, and the C=O distance is slightly shorter...

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Detalles Bibliográficos
Autores principales: Esterhuysen, Catharine, Nel, I. B. Jacques, Cronje, Stephanie
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960508/
https://www.ncbi.nlm.nih.gov/pubmed/21201603
http://dx.doi.org/10.1107/S1600536808025245
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author Esterhuysen, Catharine
Nel, I. B. Jacques
Cronje, Stephanie
author_facet Esterhuysen, Catharine
Nel, I. B. Jacques
Cronje, Stephanie
author_sort Esterhuysen, Catharine
collection PubMed
description The title compound, [HfW(C(5)H(5))(2)(C(7)H(5)O)Cl(CO)(5)] or [W(CO)(5)(C(7)H(5)O){Hf(C(5)H(5))(2)Cl}], contains two metal centres, with a (tungstenpenta­carbon­yl)oxy­phenyl­carbene unit coordinated to a hafnocene chloride. The Hf—O—C angle is nearly linear, and the C=O distance is slightly shorter than for equivalent alkoxy­carbenes. One of the cyclo­penta­dienyl (Cp) rings undergoes an offset face-to-face π–π inter­action [3.495 (7) Å] with the symmetry-related Cp ring of a neighbouring mol­ecule.
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spelling pubmed-29605082010-12-30 Penta­carbonyl-2κ(5) C-chlorido-1κCl-bis­[1(η(5))-cyclo­penta­dien­yl][μ-oxido(phenyl)methylene-1:2κ(2) O:C]hafnium(IV)tungsten(0) Esterhuysen, Catharine Nel, I. B. Jacques Cronje, Stephanie Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [HfW(C(5)H(5))(2)(C(7)H(5)O)Cl(CO)(5)] or [W(CO)(5)(C(7)H(5)O){Hf(C(5)H(5))(2)Cl}], contains two metal centres, with a (tungstenpenta­carbon­yl)oxy­phenyl­carbene unit coordinated to a hafnocene chloride. The Hf—O—C angle is nearly linear, and the C=O distance is slightly shorter than for equivalent alkoxy­carbenes. One of the cyclo­penta­dienyl (Cp) rings undergoes an offset face-to-face π–π inter­action [3.495 (7) Å] with the symmetry-related Cp ring of a neighbouring mol­ecule. International Union of Crystallography 2008-08-09 /pmc/articles/PMC2960508/ /pubmed/21201603 http://dx.doi.org/10.1107/S1600536808025245 Text en © Esterhuysen et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Esterhuysen, Catharine
Nel, I. B. Jacques
Cronje, Stephanie
Penta­carbonyl-2κ(5) C-chlorido-1κCl-bis­[1(η(5))-cyclo­penta­dien­yl][μ-oxido(phenyl)methylene-1:2κ(2) O:C]hafnium(IV)tungsten(0)
title Penta­carbonyl-2κ(5) C-chlorido-1κCl-bis­[1(η(5))-cyclo­penta­dien­yl][μ-oxido(phenyl)methylene-1:2κ(2) O:C]hafnium(IV)tungsten(0)
title_full Penta­carbonyl-2κ(5) C-chlorido-1κCl-bis­[1(η(5))-cyclo­penta­dien­yl][μ-oxido(phenyl)methylene-1:2κ(2) O:C]hafnium(IV)tungsten(0)
title_fullStr Penta­carbonyl-2κ(5) C-chlorido-1κCl-bis­[1(η(5))-cyclo­penta­dien­yl][μ-oxido(phenyl)methylene-1:2κ(2) O:C]hafnium(IV)tungsten(0)
title_full_unstemmed Penta­carbonyl-2κ(5) C-chlorido-1κCl-bis­[1(η(5))-cyclo­penta­dien­yl][μ-oxido(phenyl)methylene-1:2κ(2) O:C]hafnium(IV)tungsten(0)
title_short Penta­carbonyl-2κ(5) C-chlorido-1κCl-bis­[1(η(5))-cyclo­penta­dien­yl][μ-oxido(phenyl)methylene-1:2κ(2) O:C]hafnium(IV)tungsten(0)
title_sort penta­carbonyl-2κ(5) c-chlorido-1κcl-bis­[1(η(5))-cyclo­penta­dien­yl][μ-oxido(phenyl)methylene-1:2κ(2) o:c]hafnium(iv)tungsten(0)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960508/
https://www.ncbi.nlm.nih.gov/pubmed/21201603
http://dx.doi.org/10.1107/S1600536808025245
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AT nelibjacques pentacarbonyl2k5cchlorido1kclbis1ē5cyclopentadienylmoxidophenylmethylene12k2ochafniumivtungsten0
AT cronjestephanie pentacarbonyl2k5cchlorido1kclbis1ē5cyclopentadienylmoxidophenylmethylene12k2ochafniumivtungsten0

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