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Pentacarbonyl-2κ(5) C-chlorido-1κCl-bis[1(η(5))-cyclopentadienyl][μ-oxido(phenyl)methylene-1:2κ(2) O:C]hafnium(IV)tungsten(0)

The title compound, [HfW(C(5)H(5))(2)(C(7)H(5)O)Cl(CO)(5)] or [W(CO)(5)(C(7)H(5)O){Hf(C(5)H(5))(2)Cl}], contains two metal centres, with a (tungstenpentacarbonyl)oxyphenylcarbene unit coordinated to a hafnocene chloride. The Hf—O—C angle is nearly linear, and the C=O distance is slightly shorter...

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Detalles Bibliográficos
Autores principales:	Esterhuysen, Catharine, Nel, I. B. Jacques, Cronje, Stephanie
Formato:	Texto
Lenguaje:	English
Publicado:	International Union of Crystallography 2008
Materias:	Metal-Organic Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960508/ https://www.ncbi.nlm.nih.gov/pubmed/21201603 http://dx.doi.org/10.1107/S1600536808025245

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