Hexacarbonyl­technetium(I) perchlorate

The title compound, [Tc(CO)(6)]ClO(4), was synthesized by the reaction of [TcCl(CO)(5)] with AgClO(4), followed by acidification with HClO(4) under a CO atmosphere. The [Tc(CO)(6)](+) cation has close to idealized octa­hedral geometry, with the bond angles between cis-CO groups close to 90° and the...

Descripción completa

Detalles Bibliográficos
Autores principales: Gurzhiy, V. V., Miroslavov, A. E., Sidorenko, G. V., Lumpov, A. A., Krivovichev, S. V., Suglobov, D. N.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960579/
https://www.ncbi.nlm.nih.gov/pubmed/21201600
http://dx.doi.org/10.1107/S1600536808025208

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960579/
https://www.ncbi.nlm.nih.gov/pubmed/21201600
http://dx.doi.org/10.1107/S1600536808025208

Ejemplares similares