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Hexacarbonyltechnetium(I) perchlorate
The title compound, [Tc(CO)(6)]ClO(4), was synthesized by the reaction of [TcCl(CO)(5)] with AgClO(4), followed by acidification with HClO(4) under a CO atmosphere. The [Tc(CO)(6)](+) cation has close to idealized octahedral geometry, with the bond angles between cis-CO groups close to 90° and the...
| Autores principales: | , , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960579/ https://www.ncbi.nlm.nih.gov/pubmed/21201600 http://dx.doi.org/10.1107/S1600536808025208 |
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| author | Gurzhiy, V. V. Miroslavov, A. E. Sidorenko, G. V. Lumpov, A. A. Krivovichev, S. V. Suglobov, D. N. |
| author_facet | Gurzhiy, V. V. Miroslavov, A. E. Sidorenko, G. V. Lumpov, A. A. Krivovichev, S. V. Suglobov, D. N. |
| author_sort | Gurzhiy, V. V. |
| collection | PubMed |
| description | The title compound, [Tc(CO)(6)]ClO(4), was synthesized by the reaction of [TcCl(CO)(5)] with AgClO(4), followed by acidification with HClO(4) under a CO atmosphere. The [Tc(CO)(6)](+) cation has close to idealized octahedral geometry, with the bond angles between cis-CO groups close to 90° and the Tc—C bond lengths in the range 2.025 (3)–2.029 (3)Å. The perchlorate anion is disordered over two crystallographically equivalent half-occupied positions. The Tc atom in the [Tc(CO)(6)](+) cation is located on an inversion centre. |
| format | Text |
| id | pubmed-2960579 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29605792010-12-30 Hexacarbonyltechnetium(I) perchlorate Gurzhiy, V. V. Miroslavov, A. E. Sidorenko, G. V. Lumpov, A. A. Krivovichev, S. V. Suglobov, D. N. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Tc(CO)(6)]ClO(4), was synthesized by the reaction of [TcCl(CO)(5)] with AgClO(4), followed by acidification with HClO(4) under a CO atmosphere. The [Tc(CO)(6)](+) cation has close to idealized octahedral geometry, with the bond angles between cis-CO groups close to 90° and the Tc—C bond lengths in the range 2.025 (3)–2.029 (3)Å. The perchlorate anion is disordered over two crystallographically equivalent half-occupied positions. The Tc atom in the [Tc(CO)(6)](+) cation is located on an inversion centre. International Union of Crystallography 2008-08-09 /pmc/articles/PMC2960579/ /pubmed/21201600 http://dx.doi.org/10.1107/S1600536808025208 Text en © Gurzhiy et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Gurzhiy, V. V. Miroslavov, A. E. Sidorenko, G. V. Lumpov, A. A. Krivovichev, S. V. Suglobov, D. N. Hexacarbonyltechnetium(I) perchlorate |
| title | Hexacarbonyltechnetium(I) perchlorate |
| title_full | Hexacarbonyltechnetium(I) perchlorate |
| title_fullStr | Hexacarbonyltechnetium(I) perchlorate |
| title_full_unstemmed | Hexacarbonyltechnetium(I) perchlorate |
| title_short | Hexacarbonyltechnetium(I) perchlorate |
| title_sort | hexacarbonyltechnetium(i) perchlorate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960579/ https://www.ncbi.nlm.nih.gov/pubmed/21201600 http://dx.doi.org/10.1107/S1600536808025208 |
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