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Hexacarbonyltechnetium(I) perchlorate

The title compound, [Tc(CO)(6)]ClO(4), was synthesized by the reaction of [TcCl(CO)(5)] with AgClO(4), followed by acidification with HClO(4) under a CO atmosphere. The [Tc(CO)(6)](+) cation has close to idealized octahedral geometry, with the bond angles between cis-CO groups close to 90° and the...

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Detalles Bibliográficos
Autores principales:	Gurzhiy, V. V., Miroslavov, A. E., Sidorenko, G. V., Lumpov, A. A., Krivovichev, S. V., Suglobov, D. N.
Formato:	Texto
Lenguaje:	English
Publicado:	International Union of Crystallography 2008
Materias:	Metal-Organic Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960579/ https://www.ncbi.nlm.nih.gov/pubmed/21201600 http://dx.doi.org/10.1107/S1600536808025208

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