(5,10,15,20-Tetra­phenyl­porphyrinato-κ(4) N)(2,2,2-trifluoro-1-phenyl­ethyl­idene-κC (1))ruthenium(II): a stable fluorinated alkyl­idene complex of a ruthenium(II) porphyrin

In the title compound, [Ru(C(44)H(28)N(4))(C(8)H(5)F(3))], the fluorin­ated alkyl­idene group is bound to a five-coordinate Ru atom, which is located toward the carbene C atom, 0.3301 (5)Å from the least-squares plane of the C(20)N(4) porphyrin core. The Ru=C bond is tilted slightly from the normal...

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Detalles Bibliográficos
Autores principales: Yuge, Hidetaka, Arakawa, Natsuko, Wada, Satoko, Miyamoto, Takeshi Ken
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960679/
https://www.ncbi.nlm.nih.gov/pubmed/21201575
http://dx.doi.org/10.1107/S1600536808023374

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960679/
https://www.ncbi.nlm.nih.gov/pubmed/21201575
http://dx.doi.org/10.1107/S1600536808023374

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