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Decacarbonyl-1κ(3) C,2κ(3) C,3κ(4) C-μ-hydrido-1:2κ(2) H:H-(μ-quinoline-2-thiolato-1:2κ(2) S:S)diosmium(I)osmium(0)(3 Os—Os)
The title compound, [Os(3)(C(9)H(6)NS)H(CO)(10)], contains a nearly equilateral triangle of Os atoms. Two of the Os atoms are bridged by an S atom of the quinoline-2-thiolate ligand. Ten carbonyl groups complete the cluster, resulting in a distorted octahedral geometry for each Os atom. The hydrid...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961200/ https://www.ncbi.nlm.nih.gov/pubmed/21202167 http://dx.doi.org/10.1107/S1600536808004881 |