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Decacarbonyl-1κ(3) C,2κ(3) C,3κ(4) C-μ-hydrido-1:2κ(2) H:H-(μ-quinoline-2-thiolato-1:2κ(2) S:S)diosmium(I)osmium(0)(3 Os—Os)
The title compound, [Os(3)(C(9)H(6)NS)H(CO)(10)], contains a nearly equilateral triangle of Os atoms. Two of the Os atoms are bridged by an S atom of the quinoline-2-thiolate ligand. Ten carbonyl groups complete the cluster, resulting in a distorted octahedral geometry for each Os atom. The hydrid...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961200/ https://www.ncbi.nlm.nih.gov/pubmed/21202167 http://dx.doi.org/10.1107/S1600536808004881 |
| _version_ | 1782188925592272896 |
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| author | Sun, Yu Li, Xiu-Bing Sun, Bai-Wang |
| author_facet | Sun, Yu Li, Xiu-Bing Sun, Bai-Wang |
| author_sort | Sun, Yu |
| collection | PubMed |
| description | The title compound, [Os(3)(C(9)H(6)NS)H(CO)(10)], contains a nearly equilateral triangle of Os atoms. Two of the Os atoms are bridged by an S atom of the quinoline-2-thiolate ligand. Ten carbonyl groups complete the cluster, resulting in a distorted octahedral geometry for each Os atom. The hydride atom, which was located in a difference Fourier map and refined isotropically, bridges the shortest Os–Os edge. |
| format | Text |
| id | pubmed-2961200 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29612002010-12-30 Decacarbonyl-1κ(3) C,2κ(3) C,3κ(4) C-μ-hydrido-1:2κ(2) H:H-(μ-quinoline-2-thiolato-1:2κ(2) S:S)diosmium(I)osmium(0)(3 Os—Os) Sun, Yu Li, Xiu-Bing Sun, Bai-Wang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Os(3)(C(9)H(6)NS)H(CO)(10)], contains a nearly equilateral triangle of Os atoms. Two of the Os atoms are bridged by an S atom of the quinoline-2-thiolate ligand. Ten carbonyl groups complete the cluster, resulting in a distorted octahedral geometry for each Os atom. The hydride atom, which was located in a difference Fourier map and refined isotropically, bridges the shortest Os–Os edge. International Union of Crystallography 2008-04-02 /pmc/articles/PMC2961200/ /pubmed/21202167 http://dx.doi.org/10.1107/S1600536808004881 Text en © Sun et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Sun, Yu Li, Xiu-Bing Sun, Bai-Wang Decacarbonyl-1κ(3) C,2κ(3) C,3κ(4) C-μ-hydrido-1:2κ(2) H:H-(μ-quinoline-2-thiolato-1:2κ(2) S:S)diosmium(I)osmium(0)(3 Os—Os) |
| title | Decacarbonyl-1κ(3)
C,2κ(3)
C,3κ(4)
C-μ-hydrido-1:2κ(2)
H:H-(μ-quinoline-2-thiolato-1:2κ(2)
S:S)diosmium(I)osmium(0)(3 Os—Os) |
| title_full | Decacarbonyl-1κ(3)
C,2κ(3)
C,3κ(4)
C-μ-hydrido-1:2κ(2)
H:H-(μ-quinoline-2-thiolato-1:2κ(2)
S:S)diosmium(I)osmium(0)(3 Os—Os) |
| title_fullStr | Decacarbonyl-1κ(3)
C,2κ(3)
C,3κ(4)
C-μ-hydrido-1:2κ(2)
H:H-(μ-quinoline-2-thiolato-1:2κ(2)
S:S)diosmium(I)osmium(0)(3 Os—Os) |
| title_full_unstemmed | Decacarbonyl-1κ(3)
C,2κ(3)
C,3κ(4)
C-μ-hydrido-1:2κ(2)
H:H-(μ-quinoline-2-thiolato-1:2κ(2)
S:S)diosmium(I)osmium(0)(3 Os—Os) |
| title_short | Decacarbonyl-1κ(3)
C,2κ(3)
C,3κ(4)
C-μ-hydrido-1:2κ(2)
H:H-(μ-quinoline-2-thiolato-1:2κ(2)
S:S)diosmium(I)osmium(0)(3 Os—Os) |
| title_sort | decacarbonyl-1κ(3)
c,2κ(3)
c,3κ(4)
c-μ-hydrido-1:2κ(2)
h:h-(μ-quinoline-2-thiolato-1:2κ(2)
s:s)diosmium(i)osmium(0)(3 os—os) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961200/ https://www.ncbi.nlm.nih.gov/pubmed/21202167 http://dx.doi.org/10.1107/S1600536808004881 |
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