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Hydrogen-bonding and π–π stacking interactions in tris(1,10-phenanthroline-κ(2) N,N′)nickel(II) bis{[1-tert-butylimidazole-2(3H)-thione-κS]trichloridonickelate(II)} acetonitrile disolvate
The asymmetric unit of the title complex, [Ni(C(12)H(8)N(2))(3)][NiCl(3)(C(7)H(12)N(2)S)](2)·2CH(3)CN, consists of one anion, one-half of a cation and one acetonitrile molecule. The Ni(II) atom in the [Ni(phen)(3)](2+) cation (phen is 1,10-phenanthroline) lies on an inversion centre in an octahedr...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961703/ https://www.ncbi.nlm.nih.gov/pubmed/21202789 http://dx.doi.org/10.1107/S1600536808018060 |