O-(tert-Butyl­dimethyl­silyl)tris­(O-4-methyl­phenyl­sulfon­yl)penta­erythritol

In the title compound [systematic name: (tert-butyl­dimethyl­silyl)methane­triyl tris­(4-methyl­benzene­sulfonate)], C(32)H(44)O(10)S(3)Si, the central C atom and the Si(IV) center are in a tetra­hedral configuration. The inter­planar angles between pairs of the three benzene rings of the 4-methyl­p...

Descripción completa

Detalles Bibliográficos
Autores principales: Li, Shu-Xian, Li, Hua-Min, Lu, Zhong-Lin, Fun, Hoong-Kun, Chantrapromma, Suchada
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962104/
https://www.ncbi.nlm.nih.gov/pubmed/21203186
http://dx.doi.org/10.1107/S160053680802117X
_version_ 1782189141189984256
author Li, Shu-Xian
Li, Hua-Min
Lu, Zhong-Lin
Fun, Hoong-Kun
Chantrapromma, Suchada
author_facet Li, Shu-Xian
Li, Hua-Min
Lu, Zhong-Lin
Fun, Hoong-Kun
Chantrapromma, Suchada
author_sort Li, Shu-Xian
collection PubMed
description In the title compound [systematic name: (tert-butyl­dimethyl­silyl)methane­triyl tris­(4-methyl­benzene­sulfonate)], C(32)H(44)O(10)S(3)Si, the central C atom and the Si(IV) center are in a tetra­hedral configuration. The inter­planar angles between pairs of the three benzene rings of the 4-methyl­phenyl­sulfonyl units are 41.15 (10), 18.11 (10) and 44.09 (10)°. C—H⋯π inter­actions are observed in the crystal structure. Mol­ecules are linked into screw chains along the b axis by weak C—H⋯O inter­actions. Weak intramolecular C—H⋯O hydrogen bonds are also present.
format Text
id pubmed-2962104
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29621042010-12-30 O-(tert-Butyl­dimethyl­silyl)tris­(O-4-methyl­phenyl­sulfon­yl)penta­erythritol Li, Shu-Xian Li, Hua-Min Lu, Zhong-Lin Fun, Hoong-Kun Chantrapromma, Suchada Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound [systematic name: (tert-butyl­dimethyl­silyl)methane­triyl tris­(4-methyl­benzene­sulfonate)], C(32)H(44)O(10)S(3)Si, the central C atom and the Si(IV) center are in a tetra­hedral configuration. The inter­planar angles between pairs of the three benzene rings of the 4-methyl­phenyl­sulfonyl units are 41.15 (10), 18.11 (10) and 44.09 (10)°. C—H⋯π inter­actions are observed in the crystal structure. Mol­ecules are linked into screw chains along the b axis by weak C—H⋯O inter­actions. Weak intramolecular C—H⋯O hydrogen bonds are also present. International Union of Crystallography 2008-07-12 /pmc/articles/PMC2962104/ /pubmed/21203186 http://dx.doi.org/10.1107/S160053680802117X Text en © Li et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Shu-Xian
Li, Hua-Min
Lu, Zhong-Lin
Fun, Hoong-Kun
Chantrapromma, Suchada
O-(tert-Butyl­dimethyl­silyl)tris­(O-4-methyl­phenyl­sulfon­yl)penta­erythritol
title O-(tert-Butyl­dimethyl­silyl)tris­(O-4-methyl­phenyl­sulfon­yl)penta­erythritol
title_full O-(tert-Butyl­dimethyl­silyl)tris­(O-4-methyl­phenyl­sulfon­yl)penta­erythritol
title_fullStr O-(tert-Butyl­dimethyl­silyl)tris­(O-4-methyl­phenyl­sulfon­yl)penta­erythritol
title_full_unstemmed O-(tert-Butyl­dimethyl­silyl)tris­(O-4-methyl­phenyl­sulfon­yl)penta­erythritol
title_short O-(tert-Butyl­dimethyl­silyl)tris­(O-4-methyl­phenyl­sulfon­yl)penta­erythritol
title_sort o-(tert-butyl­dimethyl­silyl)tris­(o-4-methyl­phenyl­sulfon­yl)penta­erythritol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962104/
https://www.ncbi.nlm.nih.gov/pubmed/21203186
http://dx.doi.org/10.1107/S160053680802117X
work_keys_str_mv AT lishuxian otertbutyldimethylsilyltriso4methylphenylsulfonylpentaerythritol
AT lihuamin otertbutyldimethylsilyltriso4methylphenylsulfonylpentaerythritol
AT luzhonglin otertbutyldimethylsilyltriso4methylphenylsulfonylpentaerythritol
AT funhoongkun otertbutyldimethylsilyltriso4methylphenylsulfonylpentaerythritol
AT chantraprommasuchada otertbutyldimethylsilyltriso4methylphenylsulfonylpentaerythritol