O-(tert-Butyldimethylsilyl)tris(O-4-methylphenylsulfonyl)pentaerythritol
In the title compound [systematic name: (tert-butyldimethylsilyl)methanetriyl tris(4-methylbenzenesulfonate)], C(32)H(44)O(10)S(3)Si, the central C atom and the Si(IV) center are in a tetrahedral configuration. The interplanar angles between pairs of the three benzene rings of the 4-methylp...
Autores principales: | , , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962104/ https://www.ncbi.nlm.nih.gov/pubmed/21203186 http://dx.doi.org/10.1107/S160053680802117X |
_version_ | 1782189141189984256 |
---|---|
author | Li, Shu-Xian Li, Hua-Min Lu, Zhong-Lin Fun, Hoong-Kun Chantrapromma, Suchada |
author_facet | Li, Shu-Xian Li, Hua-Min Lu, Zhong-Lin Fun, Hoong-Kun Chantrapromma, Suchada |
author_sort | Li, Shu-Xian |
collection | PubMed |
description | In the title compound [systematic name: (tert-butyldimethylsilyl)methanetriyl tris(4-methylbenzenesulfonate)], C(32)H(44)O(10)S(3)Si, the central C atom and the Si(IV) center are in a tetrahedral configuration. The interplanar angles between pairs of the three benzene rings of the 4-methylphenylsulfonyl units are 41.15 (10), 18.11 (10) and 44.09 (10)°. C—H⋯π interactions are observed in the crystal structure. Molecules are linked into screw chains along the b axis by weak C—H⋯O interactions. Weak intramolecular C—H⋯O hydrogen bonds are also present. |
format | Text |
id | pubmed-2962104 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29621042010-12-30 O-(tert-Butyldimethylsilyl)tris(O-4-methylphenylsulfonyl)pentaerythritol Li, Shu-Xian Li, Hua-Min Lu, Zhong-Lin Fun, Hoong-Kun Chantrapromma, Suchada Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound [systematic name: (tert-butyldimethylsilyl)methanetriyl tris(4-methylbenzenesulfonate)], C(32)H(44)O(10)S(3)Si, the central C atom and the Si(IV) center are in a tetrahedral configuration. The interplanar angles between pairs of the three benzene rings of the 4-methylphenylsulfonyl units are 41.15 (10), 18.11 (10) and 44.09 (10)°. C—H⋯π interactions are observed in the crystal structure. Molecules are linked into screw chains along the b axis by weak C—H⋯O interactions. Weak intramolecular C—H⋯O hydrogen bonds are also present. International Union of Crystallography 2008-07-12 /pmc/articles/PMC2962104/ /pubmed/21203186 http://dx.doi.org/10.1107/S160053680802117X Text en © Li et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Li, Shu-Xian Li, Hua-Min Lu, Zhong-Lin Fun, Hoong-Kun Chantrapromma, Suchada O-(tert-Butyldimethylsilyl)tris(O-4-methylphenylsulfonyl)pentaerythritol |
title |
O-(tert-Butyldimethylsilyl)tris(O-4-methylphenylsulfonyl)pentaerythritol |
title_full |
O-(tert-Butyldimethylsilyl)tris(O-4-methylphenylsulfonyl)pentaerythritol |
title_fullStr |
O-(tert-Butyldimethylsilyl)tris(O-4-methylphenylsulfonyl)pentaerythritol |
title_full_unstemmed |
O-(tert-Butyldimethylsilyl)tris(O-4-methylphenylsulfonyl)pentaerythritol |
title_short |
O-(tert-Butyldimethylsilyl)tris(O-4-methylphenylsulfonyl)pentaerythritol |
title_sort | o-(tert-butyldimethylsilyl)tris(o-4-methylphenylsulfonyl)pentaerythritol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962104/ https://www.ncbi.nlm.nih.gov/pubmed/21203186 http://dx.doi.org/10.1107/S160053680802117X |
work_keys_str_mv | AT lishuxian otertbutyldimethylsilyltriso4methylphenylsulfonylpentaerythritol AT lihuamin otertbutyldimethylsilyltriso4methylphenylsulfonylpentaerythritol AT luzhonglin otertbutyldimethylsilyltriso4methylphenylsulfonylpentaerythritol AT funhoongkun otertbutyldimethylsilyltriso4methylphenylsulfonylpentaerythritol AT chantraprommasuchada otertbutyldimethylsilyltriso4methylphenylsulfonylpentaerythritol |