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Pentacarbonyl-2κ(5) C-chlorido-1κCl-bis[1(η(5))-cyclopentadienyl](μ-1-oxidoethylene-1:2κ(2) O:C)chromium(0)zirconium(IV)
The title compound, [CrZr(C(5)H(5))(2)(C(2)H(3)O)Cl(CO)(5)], consists of two metal centres, with a (pentacarbonylchromium)oxymethylcarbene group coordinating as a monodentate ligand to the zirconocene chloride. π-Delocalization through the Zr—O—C=Cr unit is indicated by a short Zr—O distance [2.0...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968157/ https://www.ncbi.nlm.nih.gov/pubmed/21581744 http://dx.doi.org/10.1107/S1600536808042621 |