Penta­carbonyl-2κ(5) C-chlorido-1κCl-bis­[1(η(5))-cyclo­penta­dien­yl](μ-1-oxido­ethyl­ene-1:2κ(2) O:C)chromium(0)zirconium(IV)

The title compound, [CrZr(C(5)H(5))(2)(C(2)H(3)O)Cl(CO)(5)], consists of two metal centres, with a (penta­carbonyl­chromium)oxymethyl­carbene group coordinating as a monodentate ligand to the zirconocene chloride. π-Delocalization through the Zr—O—C=Cr unit is indicated by a short Zr—O distance [2.0...

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Autores principales: Esterhuysen, Catharine, Retief, Lizette, Kruger, Gert J., Cronje, Stephanie, Raubenheimer, Helgard G.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968157/
https://www.ncbi.nlm.nih.gov/pubmed/21581744
http://dx.doi.org/10.1107/S1600536808042621
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author Esterhuysen, Catharine
Retief, Lizette
Kruger, Gert J.
Cronje, Stephanie
Raubenheimer, Helgard G.
author_facet Esterhuysen, Catharine
Retief, Lizette
Kruger, Gert J.
Cronje, Stephanie
Raubenheimer, Helgard G.
author_sort Esterhuysen, Catharine
collection PubMed
description The title compound, [CrZr(C(5)H(5))(2)(C(2)H(3)O)Cl(CO)(5)], consists of two metal centres, with a (penta­carbonyl­chromium)oxymethyl­carbene group coordinating as a monodentate ligand to the zirconocene chloride. π-Delocalization through the Zr—O—C=Cr unit is indicated by a short Zr—O distance [2.041 (3) Å] and a nearly linear Zr—O—C angle [170.5 (3)°]. Mol­ecules are aligned with their mol­ecular planes (through Zr, Cl, carbene and Cr) parallel to the ab plane. C—H⋯Cl inter­actions result in zigzag chains of mol­ecules propagating parallel to the b axis.
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spelling pubmed-29681572010-12-30 Penta­carbonyl-2κ(5) C-chlorido-1κCl-bis­[1(η(5))-cyclo­penta­dien­yl](μ-1-oxido­ethyl­ene-1:2κ(2) O:C)chromium(0)zirconium(IV) Esterhuysen, Catharine Retief, Lizette Kruger, Gert J. Cronje, Stephanie Raubenheimer, Helgard G. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [CrZr(C(5)H(5))(2)(C(2)H(3)O)Cl(CO)(5)], consists of two metal centres, with a (penta­carbonyl­chromium)oxymethyl­carbene group coordinating as a monodentate ligand to the zirconocene chloride. π-Delocalization through the Zr—O—C=Cr unit is indicated by a short Zr—O distance [2.041 (3) Å] and a nearly linear Zr—O—C angle [170.5 (3)°]. Mol­ecules are aligned with their mol­ecular planes (through Zr, Cl, carbene and Cr) parallel to the ab plane. C—H⋯Cl inter­actions result in zigzag chains of mol­ecules propagating parallel to the b axis. International Union of Crystallography 2009-01-08 /pmc/articles/PMC2968157/ /pubmed/21581744 http://dx.doi.org/10.1107/S1600536808042621 Text en © Esterhuysen et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Esterhuysen, Catharine
Retief, Lizette
Kruger, Gert J.
Cronje, Stephanie
Raubenheimer, Helgard G.
Penta­carbonyl-2κ(5) C-chlorido-1κCl-bis­[1(η(5))-cyclo­penta­dien­yl](μ-1-oxido­ethyl­ene-1:2κ(2) O:C)chromium(0)zirconium(IV)
title Penta­carbonyl-2κ(5) C-chlorido-1κCl-bis­[1(η(5))-cyclo­penta­dien­yl](μ-1-oxido­ethyl­ene-1:2κ(2) O:C)chromium(0)zirconium(IV)
title_full Penta­carbonyl-2κ(5) C-chlorido-1κCl-bis­[1(η(5))-cyclo­penta­dien­yl](μ-1-oxido­ethyl­ene-1:2κ(2) O:C)chromium(0)zirconium(IV)
title_fullStr Penta­carbonyl-2κ(5) C-chlorido-1κCl-bis­[1(η(5))-cyclo­penta­dien­yl](μ-1-oxido­ethyl­ene-1:2κ(2) O:C)chromium(0)zirconium(IV)
title_full_unstemmed Penta­carbonyl-2κ(5) C-chlorido-1κCl-bis­[1(η(5))-cyclo­penta­dien­yl](μ-1-oxido­ethyl­ene-1:2κ(2) O:C)chromium(0)zirconium(IV)
title_short Penta­carbonyl-2κ(5) C-chlorido-1κCl-bis­[1(η(5))-cyclo­penta­dien­yl](μ-1-oxido­ethyl­ene-1:2κ(2) O:C)chromium(0)zirconium(IV)
title_sort penta­carbonyl-2κ(5) c-chlorido-1κcl-bis­[1(η(5))-cyclo­penta­dien­yl](μ-1-oxido­ethyl­ene-1:2κ(2) o:c)chromium(0)zirconium(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968157/
https://www.ncbi.nlm.nih.gov/pubmed/21581744
http://dx.doi.org/10.1107/S1600536808042621
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AT cronjestephanie pentacarbonyl2k5cchlorido1kclbis1ē5cyclopentadienylm1oxidoethylene12k2occhromium0zirconiumiv
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