{6,6′-Dimethoxy-2,2′-[4-bromo-o-phenylenebis(nitrilomethylidyne)]diphenolato}nickel(II) methanol solvate
In the title compound, [Ni(C(22)H(17)BrN(2)O(4))]·CH(3)OH, the Ni(II) ion is in a slightly distorted square-planar geometry involving an N(2)O(2) atom set of the tetradentate Schiff base ligand. The asymmetric unit contains one nickel complex and one methanol solvent molecule. The dihedral angle b...
Autores principales: | , , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968362/ https://www.ncbi.nlm.nih.gov/pubmed/21581816 http://dx.doi.org/10.1107/S1600536809002104 |
_version_ | 1782189852388753408 |
---|---|
author | Yu, Ming-Ming Xu, Hong Shi, Qiu-Zhi Wei, Ying-Nai Li, Zhan-Xian |
author_facet | Yu, Ming-Ming Xu, Hong Shi, Qiu-Zhi Wei, Ying-Nai Li, Zhan-Xian |
author_sort | Yu, Ming-Ming |
collection | PubMed |
description | In the title compound, [Ni(C(22)H(17)BrN(2)O(4))]·CH(3)OH, the Ni(II) ion is in a slightly distorted square-planar geometry involving an N(2)O(2) atom set of the tetradentate Schiff base ligand. The asymmetric unit contains one nickel complex and one methanol solvent molecule. The dihedral angle between the aromatic ring planes of the central aromatic ring and other two aromatic rings are 10.8 (3) and 6.0 (2)°. The crystal structure is stabilized by intermolecular C—H⋯O and C—H⋯Br and by intramolecular O—H⋯O hydrogen bonds. |
format | Text |
id | pubmed-2968362 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29683622010-12-30 {6,6′-Dimethoxy-2,2′-[4-bromo-o-phenylenebis(nitrilomethylidyne)]diphenolato}nickel(II) methanol solvate Yu, Ming-Ming Xu, Hong Shi, Qiu-Zhi Wei, Ying-Nai Li, Zhan-Xian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(22)H(17)BrN(2)O(4))]·CH(3)OH, the Ni(II) ion is in a slightly distorted square-planar geometry involving an N(2)O(2) atom set of the tetradentate Schiff base ligand. The asymmetric unit contains one nickel complex and one methanol solvent molecule. The dihedral angle between the aromatic ring planes of the central aromatic ring and other two aromatic rings are 10.8 (3) and 6.0 (2)°. The crystal structure is stabilized by intermolecular C—H⋯O and C—H⋯Br and by intramolecular O—H⋯O hydrogen bonds. International Union of Crystallography 2009-01-23 /pmc/articles/PMC2968362/ /pubmed/21581816 http://dx.doi.org/10.1107/S1600536809002104 Text en © Yu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yu, Ming-Ming Xu, Hong Shi, Qiu-Zhi Wei, Ying-Nai Li, Zhan-Xian {6,6′-Dimethoxy-2,2′-[4-bromo-o-phenylenebis(nitrilomethylidyne)]diphenolato}nickel(II) methanol solvate |
title | {6,6′-Dimethoxy-2,2′-[4-bromo-o-phenylenebis(nitrilomethylidyne)]diphenolato}nickel(II) methanol solvate |
title_full | {6,6′-Dimethoxy-2,2′-[4-bromo-o-phenylenebis(nitrilomethylidyne)]diphenolato}nickel(II) methanol solvate |
title_fullStr | {6,6′-Dimethoxy-2,2′-[4-bromo-o-phenylenebis(nitrilomethylidyne)]diphenolato}nickel(II) methanol solvate |
title_full_unstemmed | {6,6′-Dimethoxy-2,2′-[4-bromo-o-phenylenebis(nitrilomethylidyne)]diphenolato}nickel(II) methanol solvate |
title_short | {6,6′-Dimethoxy-2,2′-[4-bromo-o-phenylenebis(nitrilomethylidyne)]diphenolato}nickel(II) methanol solvate |
title_sort | {6,6′-dimethoxy-2,2′-[4-bromo-o-phenylenebis(nitrilomethylidyne)]diphenolato}nickel(ii) methanol solvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968362/ https://www.ncbi.nlm.nih.gov/pubmed/21581816 http://dx.doi.org/10.1107/S1600536809002104 |
work_keys_str_mv | AT yumingming 66dimethoxy224bromoophenylenebisnitrilomethylidynediphenolatonickeliimethanolsolvate AT xuhong 66dimethoxy224bromoophenylenebisnitrilomethylidynediphenolatonickeliimethanolsolvate AT shiqiuzhi 66dimethoxy224bromoophenylenebisnitrilomethylidynediphenolatonickeliimethanolsolvate AT weiyingnai 66dimethoxy224bromoophenylenebisnitrilomethylidynediphenolatonickeliimethanolsolvate AT lizhanxian 66dimethoxy224bromoophenylenebisnitrilomethylidynediphenolatonickeliimethanolsolvate |