{6,6′-Dimeth­oxy-2,2′-[4-bromo-o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}nickel(II) methanol solvate

In the title compound, [Ni(C(22)H(17)BrN(2)O(4))]·CH(3)OH, the Ni(II) ion is in a slightly distorted square-planar geometry involving an N(2)O(2) atom set of the tetra­dentate Schiff base ligand. The asymmetric unit contains one nickel complex and one methanol solvent mol­ecule. The dihedral angle b...

Descripción completa

Detalles Bibliográficos
Autores principales: Yu, Ming-Ming, Xu, Hong, Shi, Qiu-Zhi, Wei, Ying-Nai, Li, Zhan-Xian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968362/
https://www.ncbi.nlm.nih.gov/pubmed/21581816
http://dx.doi.org/10.1107/S1600536809002104
_version_ 1782189852388753408
author Yu, Ming-Ming
Xu, Hong
Shi, Qiu-Zhi
Wei, Ying-Nai
Li, Zhan-Xian
author_facet Yu, Ming-Ming
Xu, Hong
Shi, Qiu-Zhi
Wei, Ying-Nai
Li, Zhan-Xian
author_sort Yu, Ming-Ming
collection PubMed
description In the title compound, [Ni(C(22)H(17)BrN(2)O(4))]·CH(3)OH, the Ni(II) ion is in a slightly distorted square-planar geometry involving an N(2)O(2) atom set of the tetra­dentate Schiff base ligand. The asymmetric unit contains one nickel complex and one methanol solvent mol­ecule. The dihedral angle between the aromatic ring planes of the central aromatic ring and other two aromatic rings are 10.8 (3) and 6.0 (2)°. The crystal structure is stabilized by inter­molecular C—H⋯O and C—H⋯Br and by intra­molecular O—H⋯O hydrogen bonds.
format Text
id pubmed-2968362
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29683622010-12-30 {6,6′-Dimeth­oxy-2,2′-[4-bromo-o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}nickel(II) methanol solvate Yu, Ming-Ming Xu, Hong Shi, Qiu-Zhi Wei, Ying-Nai Li, Zhan-Xian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(22)H(17)BrN(2)O(4))]·CH(3)OH, the Ni(II) ion is in a slightly distorted square-planar geometry involving an N(2)O(2) atom set of the tetra­dentate Schiff base ligand. The asymmetric unit contains one nickel complex and one methanol solvent mol­ecule. The dihedral angle between the aromatic ring planes of the central aromatic ring and other two aromatic rings are 10.8 (3) and 6.0 (2)°. The crystal structure is stabilized by inter­molecular C—H⋯O and C—H⋯Br and by intra­molecular O—H⋯O hydrogen bonds. International Union of Crystallography 2009-01-23 /pmc/articles/PMC2968362/ /pubmed/21581816 http://dx.doi.org/10.1107/S1600536809002104 Text en © Yu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yu, Ming-Ming
Xu, Hong
Shi, Qiu-Zhi
Wei, Ying-Nai
Li, Zhan-Xian
{6,6′-Dimeth­oxy-2,2′-[4-bromo-o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}nickel(II) methanol solvate
title {6,6′-Dimeth­oxy-2,2′-[4-bromo-o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}nickel(II) methanol solvate
title_full {6,6′-Dimeth­oxy-2,2′-[4-bromo-o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}nickel(II) methanol solvate
title_fullStr {6,6′-Dimeth­oxy-2,2′-[4-bromo-o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}nickel(II) methanol solvate
title_full_unstemmed {6,6′-Dimeth­oxy-2,2′-[4-bromo-o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}nickel(II) methanol solvate
title_short {6,6′-Dimeth­oxy-2,2′-[4-bromo-o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}nickel(II) methanol solvate
title_sort {6,6′-dimeth­oxy-2,2′-[4-bromo-o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}nickel(ii) methanol solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968362/
https://www.ncbi.nlm.nih.gov/pubmed/21581816
http://dx.doi.org/10.1107/S1600536809002104
work_keys_str_mv AT yumingming 66dimethoxy224bromoophenylenebisnitrilomethylidynediphenolatonickeliimethanolsolvate
AT xuhong 66dimethoxy224bromoophenylenebisnitrilomethylidynediphenolatonickeliimethanolsolvate
AT shiqiuzhi 66dimethoxy224bromoophenylenebisnitrilomethylidynediphenolatonickeliimethanolsolvate
AT weiyingnai 66dimethoxy224bromoophenylenebisnitrilomethylidynediphenolatonickeliimethanolsolvate
AT lizhanxian 66dimethoxy224bromoophenylenebisnitrilomethylidynediphenolatonickeliimethanolsolvate