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Chlorido[2,15-dimethyl-3,7,10,14,20-pentaazabicyclo[14.3.1]eicosa-1(20),2,14,16,18-pentaene]manganese(II) perchlorate acetonitrile solvate
The Mn ion in the title complex, [MnCl(C(17)H(27)N(5))]ClO(4)·CH(3)CN, is six-coordinated with a geometry intermediate between pentagonal pyramidal and heavily distorted octahedral. In the macrocycle, the pyridinium ring makes a large dihedral angle of 63.70 (9)° with the best plane through the r...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968472/ https://www.ncbi.nlm.nih.gov/pubmed/21582074 http://dx.doi.org/10.1107/S1600536809005595 |