Chlorido[2,15-dimethyl-3,7,10,14,20-penta­azabicyclo­[14.3.1]eicosa-1(20),2,14,16,18-penta­ene]manganese(II) perchlorate acetonitrile solvate

The Mn ion in the title complex, [MnCl(C(17)H(27)N(5))]ClO(4)·CH(3)CN, is six-coordinated with a geometry inter­mediate between penta­gonal pyramidal and heavily distorted octa­hedral. In the macrocycle, the pyridinium ring makes a large dihedral angle of 63.70 (9)° with the best plane through the r...

Descripción completa

Detalles Bibliográficos
Autores principales: Głowińska, Agnieszka, Patroniak, Violetta, Radecka-Paryzek, Wanda, Kubicki, Maciej
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968472/
https://www.ncbi.nlm.nih.gov/pubmed/21582074
http://dx.doi.org/10.1107/S1600536809005595
_version_ 1782189887228739584
author Głowińska, Agnieszka
Patroniak, Violetta
Radecka-Paryzek, Wanda
Kubicki, Maciej
author_facet Głowińska, Agnieszka
Patroniak, Violetta
Radecka-Paryzek, Wanda
Kubicki, Maciej
author_sort Głowińska, Agnieszka
collection PubMed
description The Mn ion in the title complex, [MnCl(C(17)H(27)N(5))]ClO(4)·CH(3)CN, is six-coordinated with a geometry inter­mediate between penta­gonal pyramidal and heavily distorted octa­hedral. In the macrocycle, the pyridinium ring makes a large dihedral angle of 63.70 (9)° with the best plane through the remaining four N atoms. This feature is common for 17-membered N(5) rings, in contrast to their 16- and 15-membered analogues which often form planar N(5) systems. In the crystal, N—H⋯O and C—H⋯O interactions help to establish the packing. The perchlorate counter-ion is rotationally disordered around the chlorine centre, with occupation factors of 0.74 (1) and 0.26 (1).
format Text
id pubmed-2968472
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29684722010-12-30 Chlorido[2,15-dimethyl-3,7,10,14,20-penta­azabicyclo­[14.3.1]eicosa-1(20),2,14,16,18-penta­ene]manganese(II) perchlorate acetonitrile solvate Głowińska, Agnieszka Patroniak, Violetta Radecka-Paryzek, Wanda Kubicki, Maciej Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Mn ion in the title complex, [MnCl(C(17)H(27)N(5))]ClO(4)·CH(3)CN, is six-coordinated with a geometry inter­mediate between penta­gonal pyramidal and heavily distorted octa­hedral. In the macrocycle, the pyridinium ring makes a large dihedral angle of 63.70 (9)° with the best plane through the remaining four N atoms. This feature is common for 17-membered N(5) rings, in contrast to their 16- and 15-membered analogues which often form planar N(5) systems. In the crystal, N—H⋯O and C—H⋯O interactions help to establish the packing. The perchlorate counter-ion is rotationally disordered around the chlorine centre, with occupation factors of 0.74 (1) and 0.26 (1). International Union of Crystallography 2009-02-21 /pmc/articles/PMC2968472/ /pubmed/21582074 http://dx.doi.org/10.1107/S1600536809005595 Text en © Głowińska et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Głowińska, Agnieszka
Patroniak, Violetta
Radecka-Paryzek, Wanda
Kubicki, Maciej
Chlorido[2,15-dimethyl-3,7,10,14,20-penta­azabicyclo­[14.3.1]eicosa-1(20),2,14,16,18-penta­ene]manganese(II) perchlorate acetonitrile solvate
title Chlorido[2,15-dimethyl-3,7,10,14,20-penta­azabicyclo­[14.3.1]eicosa-1(20),2,14,16,18-penta­ene]manganese(II) perchlorate acetonitrile solvate
title_full Chlorido[2,15-dimethyl-3,7,10,14,20-penta­azabicyclo­[14.3.1]eicosa-1(20),2,14,16,18-penta­ene]manganese(II) perchlorate acetonitrile solvate
title_fullStr Chlorido[2,15-dimethyl-3,7,10,14,20-penta­azabicyclo­[14.3.1]eicosa-1(20),2,14,16,18-penta­ene]manganese(II) perchlorate acetonitrile solvate
title_full_unstemmed Chlorido[2,15-dimethyl-3,7,10,14,20-penta­azabicyclo­[14.3.1]eicosa-1(20),2,14,16,18-penta­ene]manganese(II) perchlorate acetonitrile solvate
title_short Chlorido[2,15-dimethyl-3,7,10,14,20-penta­azabicyclo­[14.3.1]eicosa-1(20),2,14,16,18-penta­ene]manganese(II) perchlorate acetonitrile solvate
title_sort chlorido[2,15-dimethyl-3,7,10,14,20-penta­azabicyclo­[14.3.1]eicosa-1(20),2,14,16,18-penta­ene]manganese(ii) perchlorate acetonitrile solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968472/
https://www.ncbi.nlm.nih.gov/pubmed/21582074
http://dx.doi.org/10.1107/S1600536809005595
work_keys_str_mv AT głowinskaagnieszka chlorido215dimethyl37101420pentaazabicyclo1431eicosa1202141618pentaenemanganeseiiperchlorateacetonitrilesolvate
AT patroniakvioletta chlorido215dimethyl37101420pentaazabicyclo1431eicosa1202141618pentaenemanganeseiiperchlorateacetonitrilesolvate
AT radeckaparyzekwanda chlorido215dimethyl37101420pentaazabicyclo1431eicosa1202141618pentaenemanganeseiiperchlorateacetonitrilesolvate
AT kubickimaciej chlorido215dimethyl37101420pentaazabicyclo1431eicosa1202141618pentaenemanganeseiiperchlorateacetonitrilesolvate

Ejemplares similares