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(S (P),S (P))-(–)-(E)-1,2-Bis(methyl­phenyl­phosphino­yl)ethene

The title compound, C(16)H(18)O(2)P(2), possesses two stereogenic P atoms and shows a distorted s–cis conformation of each O=P—C=C moiety. This has been suggested on the basis of the stereochemical result of 1,3-dipolar cyclo­additions with nitro­nes and is now confirmed by the present crystal struc...

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Detalles Bibliográficos
Autores principales: Butenschön, Holger, Vinokurov, Nikolai, Baumgardt, Ingmar, Pietrusiewicz, K. Michal
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968589/
https://www.ncbi.nlm.nih.gov/pubmed/21582180
http://dx.doi.org/10.1107/S1600536809004632