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{2,2-Bis[(4S)-4-tert-butyl-4,5-dihydro-1,3-oxazol-2-yl]propane}bis­(N,N-di­methyl­formamide)copper(II) bis­(hexa­fluoridoantimonate)

In the title compound, [Cu(C(17)H(30)N(2)O(2))(C(3)H(7)NO)(2)][SbF(6)](2), which is a potential catalyst in the asymmetric Gosteli–Claisen rearrangement, the Cu atom adopts a distorted cis-CuN(2)O(2) square-planar geometry arising from N,N′-bidentate coordin­ation by the chiral ligand and two O-bond...

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Detalles Bibliográficos
Autores principales: Rehbein, Julia, Schürmann, Markus, Preut, Hans, Hiersemann, Martin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969361/
https://www.ncbi.nlm.nih.gov/pubmed/21582678
http://dx.doi.org/10.1107/S1600536809020364