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{2,2-Bis[(4S)-4-tert-butyl-4,5-dihydro-1,3-oxazol-2-yl]propane}bis(N,N-dimethylformamide)copper(II) bis(hexafluoridoantimonate)
In the title compound, [Cu(C(17)H(30)N(2)O(2))(C(3)H(7)NO)(2)][SbF(6)](2), which is a potential catalyst in the asymmetric Gosteli–Claisen rearrangement, the Cu atom adopts a distorted cis-CuN(2)O(2) square-planar geometry arising from N,N′-bidentate coordination by the chiral ligand and two O-bond...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969361/ https://www.ncbi.nlm.nih.gov/pubmed/21582678 http://dx.doi.org/10.1107/S1600536809020364 |
| _version_ | 1782190125979009024 |
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| author | Rehbein, Julia Schürmann, Markus Preut, Hans Hiersemann, Martin |
| author_facet | Rehbein, Julia Schürmann, Markus Preut, Hans Hiersemann, Martin |
| author_sort | Rehbein, Julia |
| collection | PubMed |
| description | In the title compound, [Cu(C(17)H(30)N(2)O(2))(C(3)H(7)NO)(2)][SbF(6)](2), which is a potential catalyst in the asymmetric Gosteli–Claisen rearrangement, the Cu atom adopts a distorted cis-CuN(2)O(2) square-planar geometry arising from N,N′-bidentate coordination by the chiral ligand and two O-bonded dimethylformamide molecules. Two short C—H⋯O contacts occur within the ligand and two weak intermolecular C—H⋯F bonds may help to establish the packing. |
| format | Text |
| id | pubmed-2969361 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29693612010-12-30 {2,2-Bis[(4S)-4-tert-butyl-4,5-dihydro-1,3-oxazol-2-yl]propane}bis(N,N-dimethylformamide)copper(II) bis(hexafluoridoantimonate) Rehbein, Julia Schürmann, Markus Preut, Hans Hiersemann, Martin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(17)H(30)N(2)O(2))(C(3)H(7)NO)(2)][SbF(6)](2), which is a potential catalyst in the asymmetric Gosteli–Claisen rearrangement, the Cu atom adopts a distorted cis-CuN(2)O(2) square-planar geometry arising from N,N′-bidentate coordination by the chiral ligand and two O-bonded dimethylformamide molecules. Two short C—H⋯O contacts occur within the ligand and two weak intermolecular C—H⋯F bonds may help to establish the packing. International Union of Crystallography 2009-06-06 /pmc/articles/PMC2969361/ /pubmed/21582678 http://dx.doi.org/10.1107/S1600536809020364 Text en © Rehbein et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Rehbein, Julia Schürmann, Markus Preut, Hans Hiersemann, Martin {2,2-Bis[(4S)-4-tert-butyl-4,5-dihydro-1,3-oxazol-2-yl]propane}bis(N,N-dimethylformamide)copper(II) bis(hexafluoridoantimonate) |
| title | {2,2-Bis[(4S)-4-tert-butyl-4,5-dihydro-1,3-oxazol-2-yl]propane}bis(N,N-dimethylformamide)copper(II) bis(hexafluoridoantimonate) |
| title_full | {2,2-Bis[(4S)-4-tert-butyl-4,5-dihydro-1,3-oxazol-2-yl]propane}bis(N,N-dimethylformamide)copper(II) bis(hexafluoridoantimonate) |
| title_fullStr | {2,2-Bis[(4S)-4-tert-butyl-4,5-dihydro-1,3-oxazol-2-yl]propane}bis(N,N-dimethylformamide)copper(II) bis(hexafluoridoantimonate) |
| title_full_unstemmed | {2,2-Bis[(4S)-4-tert-butyl-4,5-dihydro-1,3-oxazol-2-yl]propane}bis(N,N-dimethylformamide)copper(II) bis(hexafluoridoantimonate) |
| title_short | {2,2-Bis[(4S)-4-tert-butyl-4,5-dihydro-1,3-oxazol-2-yl]propane}bis(N,N-dimethylformamide)copper(II) bis(hexafluoridoantimonate) |
| title_sort | {2,2-bis[(4s)-4-tert-butyl-4,5-dihydro-1,3-oxazol-2-yl]propane}bis(n,n-dimethylformamide)copper(ii) bis(hexafluoridoantimonate) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969361/ https://www.ncbi.nlm.nih.gov/pubmed/21582678 http://dx.doi.org/10.1107/S1600536809020364 |
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