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The ansa-bridged cyclopentadienyl titanium complex [{η(5)-C(5)Me(4)CH(2)-C(NMe(2))=N}TiCl(2)]
The title complex, dichlorido[N,N-dimethyl-2-(η(5)-tetramethylcyclopentadienyl)acetamidinido-κN′]titanium(IV), [Ti(C(13)H(20)N(2))Cl(2)], exhibits an unusual ansa-bridged conformation. The cyclopentadienyl ring and the mean plane of the Ti—N=C—C—C fragment form a dihedral angle of 88.08 (11)...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969701/ https://www.ncbi.nlm.nih.gov/pubmed/21582982 http://dx.doi.org/10.1107/S1600536809015839 |