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The ansa-bridged cyclopentadienyl titanium complex [{η(5)-C(5)Me(4)CH(2)-C(NMe(2))=N}TiCl(2)]
The title complex, dichlorido[N,N-dimethyl-2-(η(5)-tetramethylcyclopentadienyl)acetamidinido-κN′]titanium(IV), [Ti(C(13)H(20)N(2))Cl(2)], exhibits an unusual ansa-bridged conformation. The cyclopentadienyl ring and the mean plane of the Ti—N=C—C—C fragment form a dihedral angle of 88.08 (11)...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969701/ https://www.ncbi.nlm.nih.gov/pubmed/21582982 http://dx.doi.org/10.1107/S1600536809015839 |
| _version_ | 1782190232502796288 |
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| author | Guo, Donglong Tong, Hong-Bo Zhou, Meisu |
| author_facet | Guo, Donglong Tong, Hong-Bo Zhou, Meisu |
| author_sort | Guo, Donglong |
| collection | PubMed |
| description | The title complex, dichlorido[N,N-dimethyl-2-(η(5)-tetramethylcyclopentadienyl)acetamidinido-κN′]titanium(IV), [Ti(C(13)H(20)N(2))Cl(2)], exhibits an unusual ansa-bridged conformation. The cyclopentadienyl ring and the mean plane of the Ti—N=C—C—C fragment form a dihedral angle of 88.08 (11)°. |
| format | Text |
| id | pubmed-2969701 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29697012010-12-30 The ansa-bridged cyclopentadienyl titanium complex [{η(5)-C(5)Me(4)CH(2)-C(NMe(2))=N}TiCl(2)] Guo, Donglong Tong, Hong-Bo Zhou, Meisu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, dichlorido[N,N-dimethyl-2-(η(5)-tetramethylcyclopentadienyl)acetamidinido-κN′]titanium(IV), [Ti(C(13)H(20)N(2))Cl(2)], exhibits an unusual ansa-bridged conformation. The cyclopentadienyl ring and the mean plane of the Ti—N=C—C—C fragment form a dihedral angle of 88.08 (11)°. International Union of Crystallography 2009-05-07 /pmc/articles/PMC2969701/ /pubmed/21582982 http://dx.doi.org/10.1107/S1600536809015839 Text en © Guo et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Guo, Donglong Tong, Hong-Bo Zhou, Meisu The ansa-bridged cyclopentadienyl titanium complex [{η(5)-C(5)Me(4)CH(2)-C(NMe(2))=N}TiCl(2)] |
| title | The ansa-bridged cyclopentadienyl titanium complex [{η(5)-C(5)Me(4)CH(2)-C(NMe(2))=N}TiCl(2)] |
| title_full | The ansa-bridged cyclopentadienyl titanium complex [{η(5)-C(5)Me(4)CH(2)-C(NMe(2))=N}TiCl(2)] |
| title_fullStr | The ansa-bridged cyclopentadienyl titanium complex [{η(5)-C(5)Me(4)CH(2)-C(NMe(2))=N}TiCl(2)] |
| title_full_unstemmed | The ansa-bridged cyclopentadienyl titanium complex [{η(5)-C(5)Me(4)CH(2)-C(NMe(2))=N}TiCl(2)] |
| title_short | The ansa-bridged cyclopentadienyl titanium complex [{η(5)-C(5)Me(4)CH(2)-C(NMe(2))=N}TiCl(2)] |
| title_sort | ansa-bridged cyclopentadienyl titanium complex [{η(5)-c(5)me(4)ch(2)-c(nme(2))=n}ticl(2)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969701/ https://www.ncbi.nlm.nih.gov/pubmed/21582982 http://dx.doi.org/10.1107/S1600536809015839 |
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