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The ansa-bridged cyclopentadienyl titanium complex [{η(5)-C(5)Me(4)CH(2)-C(NMe(2))=N}TiCl(2)]

The title complex, dichlorido[N,N-dimethyl-2-(η(5)-tetramethylcyclopentadienyl)acetamidinido-κN′]titanium(IV), [Ti(C(13)H(20)N(2))Cl(2)], exhibits an unusual ansa-bridged conformation. The cyclopentadienyl ring and the mean plane of the Ti—N=C—C—C fragment form a dihedral angle of 88.08 (11)...

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Detalles Bibliográficos
Autores principales:	Guo, Donglong, Tong, Hong-Bo, Zhou, Meisu
Formato:	Texto
Lenguaje:	English
Publicado:	International Union of Crystallography 2009
Materias:	Metal-Organic Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969701/ https://www.ncbi.nlm.nih.gov/pubmed/21582982 http://dx.doi.org/10.1107/S1600536809015839

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