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Di-μ-cyanido-1:2κ(2) C:N,2:3κ(2) N:C-hexa­cyanido-1κ(3) C,3κ(3) C-tetra­kis(1,10-phenanthroline)-1κ(2) N,N′;2κ(4) N,N′;3κ(2) N,N′-1,3-dicobalt(III)-2-iron(II) tetra­hydrate

The hydro­thermal reaction of CoCl(2)·6H(2)O, 1,10-phenanthroline (phen) and K(3)[Fe(CN)(6)] in deionized water yielded the title cyanide-bridged trinuclear cluster, [Co(2)Fe(CN)(8)(C(12)H(8)N(2))(4)]·4H(2)O or [{Co(III)(phen)(CN)(4)}(2){Fe(II)(phen)(2)}]·4H(2)O, which contains two Co(III) centers a...

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Detalles Bibliográficos
Autores principales: Zhang, Ying, Yuan, Ai-Hua, Zhou, Hu, Guo, Ji-Xi, Liu, Lang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970114/
https://www.ncbi.nlm.nih.gov/pubmed/21577399
http://dx.doi.org/10.1107/S1600536809030165