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Carbonyl­chlorido(1-methyl­sulfanylpenta-1,3-dien-1-yl-5-yl­idene)bis­(triphenyl­phosphane)osmium(II)

The crystal structure of the title compound, [Os(C(6)H(7)S)Cl(C(18)H(15)P)(2)(CO)], confirms the formulation as an osmabenzene. There is a slightly distorted octa­hedral coordination environment at the Os(II) ion, with the triphenyl­phosphane ligands mutually trans and the chloride cis to the carbon...

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Detalles Bibliográficos
Autores principales: Johns, Paul M., Roper, Warren R., Woodgate, Scott D., Wright, L. James
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971168/
https://www.ncbi.nlm.nih.gov/pubmed/21578082
http://dx.doi.org/10.1107/S1600536809039695