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Carbonylchlorido(1-methylsulfanylpenta-1,3-dien-1-yl-5-ylidene)bis(triphenylphosphane)osmium(II)
The crystal structure of the title compound, [Os(C(6)H(7)S)Cl(C(18)H(15)P)(2)(CO)], confirms the formulation as an osmabenzene. There is a slightly distorted octahedral coordination environment at the Os(II) ion, with the triphenylphosphane ligands mutually trans and the chloride cis to the carbon...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971168/ https://www.ncbi.nlm.nih.gov/pubmed/21578082 http://dx.doi.org/10.1107/S1600536809039695 |