Tri-μ-ethanethiol­ato-bis­{[η(5)-1,2,3,4-tetra­methyl-5-(trimethyl­silyl)cyclo­penta­dien­yl]iron(II,III)}(Fe(II)–Fe(III))

The title complex, [Fe(2)(C(2)H(5)S)(3)(C(12)H(21)Si)(2)], has an unusual Fe(2)S(3) core. The two 1,2,3,4-tetra­methyl-5-(trimethyl­silyl)cyclo­penta­dienyl (Cp′) ligands coordinate to the Fe atoms with their C(5) planes perpendicular [dihedral angles = 88.23 (7) and 88.55 (7)°] to the Fe—Fe vector,...

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Detalles Bibliográficos
Autor principal: Li, Jing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972053/
https://www.ncbi.nlm.nih.gov/pubmed/21578582
http://dx.doi.org/10.1107/S1600536809045735

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972053/
https://www.ncbi.nlm.nih.gov/pubmed/21578582
http://dx.doi.org/10.1107/S1600536809045735

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