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Use of N-Methylformamide as a Solvent in Indium-Promoted Barbier Reactions en Route to Enediyne and Epoxy Diyne Formation: Comparison of Rate and Stereoselectivity in C−C Bond-Forming Reactions with Water
[Image: see text] Indium-promoted coupling reactions between propargyl aldehydes (1) and α-chloropropargylphenyl sulfide are reported. Although water has been shown to accelerate indium metal promoted reactions, the reverse pattern was observed in this series. Use of N-methylformamide (NMF), which h...
Autores principales: | Frimpong, Kwame, Wzorek, Joseph, Lawlor, Claire, Spencer, Katharine, Mitzel, Thomas |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2976581/ https://www.ncbi.nlm.nih.gov/pubmed/19634900 http://dx.doi.org/10.1021/jo900763u |
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