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[3,3′-Dimesityl-1,1′-(4,5:16,17-dibenzo-3,6,9,12,15,18-hexa­oxaeicosane-1,20-di­yl)diimidazolin-2-yl­idene]dithio­cyanato­palladium(II)

The coordination geometry of the Pd atom in the title compound, [Pd(SCN)(2)(C(46)H(54)N(4)O(6))], is approximately square-planar. The N-heterocyclic carbene (NHC) metallacrown ether ligand binds to the Pd atom in a trans orientation through the carbene C atoms of the two imidazole rings and generate...

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Detalles Bibliográficos
Autores principales: Zhang, Xiao-Qin, Luo, Mei-Ming
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977613/
https://www.ncbi.nlm.nih.gov/pubmed/21583799
http://dx.doi.org/10.1107/S1600536809014615