[3,3′-Dimesityl-1,1′-(4,5:16,17-dibenzo-3,6,9,12,15,18-hexa­oxaeicosane-1,20-di­yl)diimidazolin-2-yl­idene]dithio­cyanato­palladium(II)

The coordination geometry of the Pd atom in the title compound, [Pd(SCN)(2)(C(46)H(54)N(4)O(6))], is approximately square-planar. The N-heterocyclic carbene (NHC) metallacrown ether ligand binds to the Pd atom in a trans orientation through the carbene C atoms of the two imidazole rings and generate...

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Detalles Bibliográficos
Autores principales: Zhang, Xiao-Qin, Luo, Mei-Ming
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977613/
https://www.ncbi.nlm.nih.gov/pubmed/21583799
http://dx.doi.org/10.1107/S1600536809014615
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author Zhang, Xiao-Qin
Luo, Mei-Ming
author_facet Zhang, Xiao-Qin
Luo, Mei-Ming
author_sort Zhang, Xiao-Qin
collection PubMed
description The coordination geometry of the Pd atom in the title compound, [Pd(SCN)(2)(C(46)H(54)N(4)O(6))], is approximately square-planar. The N-heterocyclic carbene (NHC) metallacrown ether ligand binds to the Pd atom in a trans orientation through the carbene C atoms of the two imidazole rings and generates a 25-membered chelate ring. Two mutually trans S-bound thio­cyanate ligands complete the coordination.
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spelling pubmed-29776132010-12-30 [3,3′-Dimesityl-1,1′-(4,5:16,17-dibenzo-3,6,9,12,15,18-hexa­oxaeicosane-1,20-di­yl)diimidazolin-2-yl­idene]dithio­cyanato­palladium(II) Zhang, Xiao-Qin Luo, Mei-Ming Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The coordination geometry of the Pd atom in the title compound, [Pd(SCN)(2)(C(46)H(54)N(4)O(6))], is approximately square-planar. The N-heterocyclic carbene (NHC) metallacrown ether ligand binds to the Pd atom in a trans orientation through the carbene C atoms of the two imidazole rings and generates a 25-membered chelate ring. Two mutually trans S-bound thio­cyanate ligands complete the coordination. International Union of Crystallography 2009-04-25 /pmc/articles/PMC2977613/ /pubmed/21583799 http://dx.doi.org/10.1107/S1600536809014615 Text en © Zhang and Luo 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Xiao-Qin
Luo, Mei-Ming
[3,3′-Dimesityl-1,1′-(4,5:16,17-dibenzo-3,6,9,12,15,18-hexa­oxaeicosane-1,20-di­yl)diimidazolin-2-yl­idene]dithio­cyanato­palladium(II)
title [3,3′-Dimesityl-1,1′-(4,5:16,17-dibenzo-3,6,9,12,15,18-hexa­oxaeicosane-1,20-di­yl)diimidazolin-2-yl­idene]dithio­cyanato­palladium(II)
title_full [3,3′-Dimesityl-1,1′-(4,5:16,17-dibenzo-3,6,9,12,15,18-hexa­oxaeicosane-1,20-di­yl)diimidazolin-2-yl­idene]dithio­cyanato­palladium(II)
title_fullStr [3,3′-Dimesityl-1,1′-(4,5:16,17-dibenzo-3,6,9,12,15,18-hexa­oxaeicosane-1,20-di­yl)diimidazolin-2-yl­idene]dithio­cyanato­palladium(II)
title_full_unstemmed [3,3′-Dimesityl-1,1′-(4,5:16,17-dibenzo-3,6,9,12,15,18-hexa­oxaeicosane-1,20-di­yl)diimidazolin-2-yl­idene]dithio­cyanato­palladium(II)
title_short [3,3′-Dimesityl-1,1′-(4,5:16,17-dibenzo-3,6,9,12,15,18-hexa­oxaeicosane-1,20-di­yl)diimidazolin-2-yl­idene]dithio­cyanato­palladium(II)
title_sort [3,3′-dimesityl-1,1′-(4,5:16,17-dibenzo-3,6,9,12,15,18-hexa­oxaeicosane-1,20-di­yl)diimidazolin-2-yl­idene]dithio­cyanato­palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977613/
https://www.ncbi.nlm.nih.gov/pubmed/21583799
http://dx.doi.org/10.1107/S1600536809014615
work_keys_str_mv AT zhangxiaoqin 33dimesityl11451617dibenzo369121518hexaoxaeicosane120diyldiimidazolin2ylidenedithiocyanatopalladiumii
AT luomeiming 33dimesityl11451617dibenzo369121518hexaoxaeicosane120diyldiimidazolin2ylidenedithiocyanatopalladiumii

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