tert-Butyl 2-benzoyl-2-methyl­propanoate

The title compound, C(15)H(20)O(3), is bent with a dihedral angle of 67.28 (9)° between the mean planes of the phenyl ring and a group encompassing the ester functionality (O=C—O—C). In the crystal, mol­ecules related by inversion symmetry are connected by weak C—H⋯O inter­actions into infinite chai...

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Autores principales: Logue, Marshall W., Luck, Rudy L., Maynard, Nicklaus S., Orlowski, Sandra S., Pignotti, Louis R., Putman, Annie L., Whelan, Kelli M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979963/
https://www.ncbi.nlm.nih.gov/pubmed/21579896
http://dx.doi.org/10.1107/S1600536810003120
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author Logue, Marshall W.
Luck, Rudy L.
Maynard, Nicklaus S.
Orlowski, Sandra S.
Pignotti, Louis R.
Putman, Annie L.
Whelan, Kelli M.
author_facet Logue, Marshall W.
Luck, Rudy L.
Maynard, Nicklaus S.
Orlowski, Sandra S.
Pignotti, Louis R.
Putman, Annie L.
Whelan, Kelli M.
author_sort Logue, Marshall W.
collection PubMed
description The title compound, C(15)H(20)O(3), is bent with a dihedral angle of 67.28 (9)° between the mean planes of the phenyl ring and a group encompassing the ester functionality (O=C—O—C). In the crystal, mol­ecules related by inversion symmetry are connected by weak C—H⋯O inter­actions into infinite chains. On one side of the mol­ecule there are two adjacent inter­actions between neighbouring mol­ecules involving the H atoms of methyl groups from the dimethyl groups and the O atoms of the ketone; on the other side, there are also two inter­actions to another adjacent mol­ecule involving the H atoms on the phenyl rings and the carbonyl O atoms of the ester functionality.
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spelling pubmed-29799632010-12-30 tert-Butyl 2-benzoyl-2-methyl­propanoate Logue, Marshall W. Luck, Rudy L. Maynard, Nicklaus S. Orlowski, Sandra S. Pignotti, Louis R. Putman, Annie L. Whelan, Kelli M. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(20)O(3), is bent with a dihedral angle of 67.28 (9)° between the mean planes of the phenyl ring and a group encompassing the ester functionality (O=C—O—C). In the crystal, mol­ecules related by inversion symmetry are connected by weak C—H⋯O inter­actions into infinite chains. On one side of the mol­ecule there are two adjacent inter­actions between neighbouring mol­ecules involving the H atoms of methyl groups from the dimethyl groups and the O atoms of the ketone; on the other side, there are also two inter­actions to another adjacent mol­ecule involving the H atoms on the phenyl rings and the carbonyl O atoms of the ester functionality. International Union of Crystallography 2010-01-30 /pmc/articles/PMC2979963/ /pubmed/21579896 http://dx.doi.org/10.1107/S1600536810003120 Text en © Logue et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Logue, Marshall W.
Luck, Rudy L.
Maynard, Nicklaus S.
Orlowski, Sandra S.
Pignotti, Louis R.
Putman, Annie L.
Whelan, Kelli M.
tert-Butyl 2-benzoyl-2-methyl­propanoate
title tert-Butyl 2-benzoyl-2-methyl­propanoate
title_full tert-Butyl 2-benzoyl-2-methyl­propanoate
title_fullStr tert-Butyl 2-benzoyl-2-methyl­propanoate
title_full_unstemmed tert-Butyl 2-benzoyl-2-methyl­propanoate
title_short tert-Butyl 2-benzoyl-2-methyl­propanoate
title_sort tert-butyl 2-benzoyl-2-methyl­propanoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979963/
https://www.ncbi.nlm.nih.gov/pubmed/21579896
http://dx.doi.org/10.1107/S1600536810003120
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