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β-Hydroxy carbocation intermediates in solvolyses of di- and tetra-hydronaphthalene substrates
Solvolysis of trichloroacetate esters of 2-methoxy-1,2-dihydro-1-naphthols shows a remarkably large difference in rates between the cis and trans isomers, k(cis)/k(trans) = 1800 in aqueous acetonitrile. This mirrors the behaviour of the acid-catalysed dehydration of cis- and trans-naphthalene-1,2-di...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2981814/ https://www.ncbi.nlm.nih.gov/pubmed/21085501 http://dx.doi.org/10.3762/bjoc.6.118 |