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Kinetics and mechanism of vanadium catalysed asymmetric cyanohydrin synthesis in propylene carbonate
Propylene carbonate can be used as a green solvent for the asymmetric synthesis of cyanohydrin trimethylsilyl ethers from aldehydes and trimethylsilyl cyanide catalysed by VO(salen)NCS, though reactions are slower in this solvent than the corresponding reactions carried out in dichloromethane. A mec...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
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Beilstein-Institut
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2982084/ https://www.ncbi.nlm.nih.gov/pubmed/21085513 http://dx.doi.org/10.3762/bjoc.6.119 |