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Design and synthesis of a cyclitol-derived scaffold with axial pyridyl appendages and its encapsulation of the silver(I) cation

Conversion of a myo-inositol derivative into a scyllo-inositol-derived scaffold with C(3)(v) symmetry bearing three axial pyridyl appendages is presented. This pre-organized hexadentate ligand allows complexation of silver(I). The crystal structure of the complex was established.

Detalles Bibliográficos
Autores principales: Léo, Pierre-Marc, Morin, Christophe, Philouze, Christian
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2982085/
https://www.ncbi.nlm.nih.gov/pubmed/21085514
http://dx.doi.org/10.3762/bjoc.6.115