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Design and synthesis of a cyclitol-derived scaffold with axial pyridyl appendages and its encapsulation of the silver(I) cation

Conversion of a myo-inositol derivative into a scyllo-inositol-derived scaffold with C(3)(v) symmetry bearing three axial pyridyl appendages is presented. This pre-organized hexadentate ligand allows complexation of silver(I). The crystal structure of the complex was established.

Detalles Bibliográficos
Autores principales: Léo, Pierre-Marc, Morin, Christophe, Philouze, Christian
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2982085/
https://www.ncbi.nlm.nih.gov/pubmed/21085514
http://dx.doi.org/10.3762/bjoc.6.115
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author Léo, Pierre-Marc
Morin, Christophe
Philouze, Christian
author_facet Léo, Pierre-Marc
Morin, Christophe
Philouze, Christian
author_sort Léo, Pierre-Marc
collection PubMed
description Conversion of a myo-inositol derivative into a scyllo-inositol-derived scaffold with C(3)(v) symmetry bearing three axial pyridyl appendages is presented. This pre-organized hexadentate ligand allows complexation of silver(I). The crystal structure of the complex was established.
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spelling pubmed-29820852010-11-17 Design and synthesis of a cyclitol-derived scaffold with axial pyridyl appendages and its encapsulation of the silver(I) cation Léo, Pierre-Marc Morin, Christophe Philouze, Christian Beilstein J Org Chem Letter Conversion of a myo-inositol derivative into a scyllo-inositol-derived scaffold with C(3)(v) symmetry bearing three axial pyridyl appendages is presented. This pre-organized hexadentate ligand allows complexation of silver(I). The crystal structure of the complex was established. Beilstein-Institut 2010-10-29 /pmc/articles/PMC2982085/ /pubmed/21085514 http://dx.doi.org/10.3762/bjoc.6.115 Text en Copyright © 2010, Léo et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Letter
Léo, Pierre-Marc
Morin, Christophe
Philouze, Christian
Design and synthesis of a cyclitol-derived scaffold with axial pyridyl appendages and its encapsulation of the silver(I) cation
title Design and synthesis of a cyclitol-derived scaffold with axial pyridyl appendages and its encapsulation of the silver(I) cation
title_full Design and synthesis of a cyclitol-derived scaffold with axial pyridyl appendages and its encapsulation of the silver(I) cation
title_fullStr Design and synthesis of a cyclitol-derived scaffold with axial pyridyl appendages and its encapsulation of the silver(I) cation
title_full_unstemmed Design and synthesis of a cyclitol-derived scaffold with axial pyridyl appendages and its encapsulation of the silver(I) cation
title_short Design and synthesis of a cyclitol-derived scaffold with axial pyridyl appendages and its encapsulation of the silver(I) cation
title_sort design and synthesis of a cyclitol-derived scaffold with axial pyridyl appendages and its encapsulation of the silver(i) cation
topic Letter
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2982085/
https://www.ncbi.nlm.nih.gov/pubmed/21085514
http://dx.doi.org/10.3762/bjoc.6.115
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