Incorporation of μ(3)-CO(3) into an Mn(III)/Mn(IV) Mn(12) cluster: {[(cyclam)Mn(IV)(μ-O)(2)Mn(III)(H(2)O)(μ-OH)](6)(μ(3)-CO(3))(2)}Cl(8)·24H(2)O

The centrosymmetric title cluster, hexa­aquadi-μ(3)-carbonato-hexa­cyclamhexa-μ(2)-hydroxido-dodeca-μ(2)-oxido-hexa­mang­an­ese(IV)hexa­manganese(III) octa­chloride tetra­cosa­hydrate, [Mn(12)(CO(3))(2)O(12)(OH)(6)(C(10)H(24)N(4))(6)(H(2)O)(6)]Cl(8)·24H(2)O, has two μ(3)-CO(3) groups that not only b...

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Detalles Bibliográficos
Autores principales: Levaton, Ben B., Olmstead, Marilyn M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983321/
https://www.ncbi.nlm.nih.gov/pubmed/21587382
http://dx.doi.org/10.1107/S1600536810034999

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983321/
https://www.ncbi.nlm.nih.gov/pubmed/21587382
http://dx.doi.org/10.1107/S1600536810034999

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