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Tetra­aqua­bis{μ(2)-2,7-bis­[(2,6-diisopropyl­phen­yl)imino­meth­yl]naphthalene-1,8-diolato}di-μ(3)-hydroxido-di-μ(2)-hydroxido-bis­(trimethyl­phosphine oxide)tetra­nickel(II)–trimethyl­phosphine oxide–diethyl ether–water (1/2/2/2)

The title complex, [Ni(4)(C(36)H(40)N(2)O(2))(2)(OH)(4)(C(3)H(9)OP)(2)(H(2)O)(4)]·2C(4)H(10)O·2C(3)H(9)OP·2H(2)O, is centrosymmetric with a central core that can be described as a defect double cubane. The four metal ions in the cluster are held together by four bridging hydroxide groups. Each Ni(II...

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Detalles Bibliográficos
Autores principales: Delferro, Massimiliano, Weberski, Michael P., Rodriguez, Brandon A., Marks, Tobin J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983651/
https://www.ncbi.nlm.nih.gov/pubmed/21580211
http://dx.doi.org/10.1107/S1600536810003697